ANTICORROSION POTENTIAL OF HYDRALAZINE FOR CORROSION OF MILD STEEL IN 1M HYDROCHLORIC ACID SOLUTION

被引:0
作者
Prasanna, B. M. [1 ]
Praveen, B. M. [2 ]
Hebbar, Narayana [3 ]
Venkatesha, T. V. [4 ]
机构
[1] Sri Taralabalu Jagadguru Inst Technol, Dept Chem, Ranebennur, India
[2] Srinivas Sch Engn, Dept Chem, Mangalore, India
[3] Bearys Inst Technol, Dept Chem, Mangalore, India
[4] Kuvempu Univ, Sch Chem Sci, Dept Studies Chem, Shankaraghatta, India
关键词
Hydralazine; Weight loss; Mild steel; Activation parameters; SEM;
D O I
暂无
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Anticorrosion potential of mild steel by Hydralazine as corrosion inhibitor for mild steel in 1M hydrochloric acid was investigated by chemical and electrochemical measurements at 303-333 K temperature. The maximum inhibition efficiency of inhibitor by Weight loss method is around 90%, Tafel polarization method is around 85%; electrochemical impedance spectroscopy measurement around 90% at 1250 ppm of Hydralazine in. The result shows that the inhibition efficiency increases with I 1M hydrochloric acid. Hydralazine acts as a mixed type inhibitor which inhibits the corrosion of mild steel due to the adsorption on metal surface. This adsorption system obeys the Langmuir adsorption isotherm. Activation parameters explains the effect of temperature with inhibition efficiency of inhibitor molecule. SEM images of inhibited mild steel strips shows a formation of passive protective film over the surface.
引用
收藏
页码:222 / 243
页数:22
相关论文
共 26 条
[1]  
Abd El-Rehim S.S., 2001, J APPL ELECTROCHEM, V31, P429
[2]  
Abd El-Rehim SSA, 1999, J APPL ELECTROCHEM, V29, P593
[3]   Benzimidazole and its derivatives as corrosion inhibitors for mild steel in 1M HCl solution [J].
Aljourani, J. ;
Raeissi, K. ;
Golozar, M. A. .
CORROSION SCIENCE, 2009, 51 (08) :1836-1843
[4]   INHIBITION OF ACID CORROSION OF STEEL BY SOME S-ALKYLISOTHIOURONIUM IODIDES [J].
ARAB, ST ;
NOOR, EA .
CORROSION, 1993, 49 (02) :122-129
[5]   Electrochemical, theoretical and XPS studies of 2-mercapto-1-methylimidazole adsorption on carbon steel in 1 M HClO4 [J].
Benali, O. ;
Larabi, L. ;
Traisnel, M. ;
Gengembre, L. ;
Harek, Y. .
APPLIED SURFACE SCIENCE, 2007, 253 (14) :6130-6139
[6]   2,5-bis(n-methoxyphenyl)-1,3,4-oxadiazoles used as corrosion inhibitors in acidic media:: correlation between inhibition efficiency and chemical structure [J].
Bentiss, F ;
Traisnel, M ;
Chaibi, N ;
Mernari, B ;
Vezin, H ;
Lagrenée, M .
CORROSION SCIENCE, 2002, 44 (10) :2271-2289
[7]   Evaluation of the inhibitor effect of L-ascorbic acid on the corrosion of mild steel [J].
Ferreira, ES ;
Giacomelli, C ;
Giacomelli, FC ;
Spinelli, A .
MATERIALS CHEMISTRY AND PHYSICS, 2004, 83 (01) :129-134
[8]   Synergistic influence of iodide ions on the inhibition of corrosion of C-steel in sulphuric acid by some aliphatic amines [J].
Fouda, AS ;
Mostafa, HA ;
El-Taib, F ;
Elewady, GY .
CORROSION SCIENCE, 2005, 47 (08) :1988-2004
[9]   THE EFFECT OF TEMPERATURE ON THE ACIDIC DISSOLUTION OF STEEL IN THE PRESENCE OF INHIBITORS [J].
KHAMIS, E .
CORROSION, 1990, 46 (06) :476-484
[10]   Experimental and theoretical study on the inhibition performance of triazole compounds for mild steel corrosion [J].
Musa, Ahmed Y. ;
Kadhum, Abdul Amir H. ;
Mohamad, Abu Bakar ;
Takriff, Mohd Sobri .
CORROSION SCIENCE, 2010, 52 (10) :3331-3340