C-13 NMR-STUDY OF ALPHA-ANOMERIC AND BETA-ANOMERIC PAIRS OF D-MANNOPYRANOSIDES AND L-RHAMNOPYRANOSIDES

被引：560
作者：
KASAI, R
OKIHARA, M
ASAKAWA, J
MIZUTANI, K
TANAKA, O
机构：
[1] Institute of Pharmaceutical Sciences, Hiroshima University School of Medicine, Kasumi, Hiroshima-shi
来源：
TETRAHEDRON | 1979年 / 35卷 / 11期
关键词：
D O I：
10.1016/0040-4020(79)85038-3
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
13C NMR spectra for a variety of α and β-anomeric series of d-mannopyranosides and l-rhamnopyranosides are presented and analyzed in comparison with those of D-glucopyranosides. The results obtained in the present study are valuable for the structure studies of plant-glycosides as well as carbohydrates, especially for determination of anomeric configurations of mannosides and rhamnosides which has been extremely difficult by other classical techniques. © 1979.
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页码：1427 / 1432
页数：6
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