GIANT ORGANOMETALLIC NETWORKS DERIVED FROM FERROCENEPOLYSULFIDES

被引：44

作者：

GALLOWAY, CP ^{[1
]}

RAUCHFUSS, TB ^{[1
]}

机构：

[1] UNIV ILLINOIS,MAT RES LAB,URBANA,IL 61801

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 09期

关键词：

D O I：

10.1002/anie.199313191

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Desulfurization with tributylphosphane converts the ferrocenepolysulfide 1 into three‐dimensional network polymers. These consist of ferrocene subunits interconnected by oligosulfide crosslinks. Gel permeation chromatography on an analogous polymerized alkyl derivative of 1 indicates molecular weights in excess of 106 Da. •=Fe. (Figure Presented.) Copyright © 1993 by VCH Verlagsgesellschaft mbH, Germany

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页码：1319 / 1321

页数：3

相关论文

共 22 条

[1] [3]FERROCENOPHANE BRIDGE REVERSAL BARRIERS .3. ENERGIES OF TE2S, TE2SE AND TE3 BRIDGED COMPOUNDS, AND A CNDO/2 INVESTIGATION OF THE MECHANISM OF THE BRIDGE REVERSAL PROCESS [J].

ABEL, EW ;

ORRELL, KG ;

OSBORNE, AG ;

SIK, V ;

WANG, GX .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 411 (1-2) :239-249

[2] ULTRASOUND-MEDIATED REDUCTIVE CONDENSATION SYNTHESIS OF SILICON SILICON BONDED NETWORK POLYMERS [J].

BIANCONI, PA ;

SCHILLING, FC ;

WEIDMAN, TW .

MACROMOLECULES, 1989, 22 (04) :1697-1704

[3] SYMMETRICALLY DISUBSTITUTED FERROCENES .1. SYNTHESIS OF POTENTIAL BIDENTATE LIGANDS [J].

BISHOP, JJ ;

DAVISON, A ;

KATCHER, ML ;

LICHTENB.DW ;

MERRILL, RE ;

SMART, JC .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1971, 27 (02) :241-&

[4] ORTHO-LITHIOTHIOPHENOL EQUIVALENTS - GENERATION, REACTIONS, AND APPLICATIONS IN SYNTHESIS OF HINDERED THIOLATE LIGANDS [J].

BLOCK, E ;

ESWARAKRISHNAN, V ;

GERNON, M ;

OFORIOKAI, G ;

SAHA, C ;

TANG, K ;

ZUBIETA, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (02) :658-665

[5] POLYFERROCENYLENE PERSULFIDES [J].

BRANDT, PF ;

RAUCHFUSS, TB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (05) :1926-1927

[6] CONFORMATIONAL ANALYSIS IN MULTISULFUR HETEROCYCLES .4. DUPLODITHIOACETONE AND 3,3 - 6,6-BIS(TETRAMETHYLENE)-S-TETRATHIANE [J].

BUSHWELL.CH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (22) :6019-+

[7]

COMPTON DL, 1993, A C S POLYMER PREPR, V34, P351

[8] SYMMETRICALLY DISUBSTITUTED FERROCENES .4. PREPARATION AND SPECTRAL STUDIES OF SOME [3]FERROCENOPHANES [J].

DAVISON, A ;

SMART, JC .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1979, 174 (03) :321-334

[9] STRUCTURE OF A TRANSITION METAL-CONTAINING POLYYNE [J].

DRAY, AE ;

RACHEL, R ;

SAXTON, WO ;

LEWIS, J ;

KHAN, MS ;

DONALD, AM ;

FRIEND, RH .

MACROMOLECULES, 1992, 25 (13) :3473-3479

[10] DIRECTED ORTHO-LITHIATION OF LITHIUM THIOPHENOLATE - NEW METHODOLOGY FOR THE PREPARATION OF ORTHO-SUBSTITUTED THIOPHENOLS AND RELATED-COMPOUNDS [J].

FIGULY, GD ;

LOOP, CK ;

MARTIN, JC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (02) :654-658