MAGNETIC-SUSCEPTIBILITY, ANISOTROPY, LOW-TEMPERATURE MAGNETIZATION AND ZERO-FIELD SPLITTING IN TETRAPHENYLPORPHYNATO IRON (III) BROMIDE

被引:28
作者
BEHERE, DV [1 ]
DATE, SK [1 ]
MITRA, S [1 ]
机构
[1] AUSTRALIAN NATL UNIV,RES SCH CHEM,CANBERRA 2600,ACT,AUSTRALIA
关键词
D O I
10.1016/0009-2614(79)87257-7
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The magnetic susceptibility (2-100 K), magnetisation (2-20 K, in an external magnetic field between 10 and 50 kOe) and paramagnetic anisotropy (80-300 K) of single crystals of high spin tetraphenylporphynato iron (III) bromide have been measured and used to deduce the zero field splitting parameter D = 13 ± 0.5 cm-1. © 1979.
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页码:544 / 548
页数:5
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