EARLY HYDRATION OF TRICALCIUN SILICATE - A SOLID REACTION WITH INDUCTION AND ACCELERATION PERIODS

被引：66

作者：

KONDO, R

DAIMON, M

机构：

[1] Research Laboratory of Engineering Materials, Tokyo Institute of Technology, Tokyo, Meguro-ku

来源：

JOURNAL OF THE AMERICAN CERAMIC SOCIETY | 1969年 / 52卷 / 09期

关键词：

D O I：

10.1111/j.1151-2916.1969.tb09203.x

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

The hydration of tricalcium silicate was studied using a sample with a limited particle size distribution. The hydration reaction was analyzed as an example of general solid reactions having induction and acceleration periods. The first product, which may have a structure similar to the reactant, forms on the surfaces of reactant grains. The nuclei of the stable product are produced in the first product layer and act as reaction centers; the main reaction to form a stable product occurs rapidly in the acceleration period. in the hydration of calcium silicates, hydrates produced in this stage are poorly crystalline and metastable and change gradually into a more stable form. Copyright © 1969, Wiley Blackwell. All rights reserved

引用

页码：503 / &

共 10 条

[1]

COPELAND LE, 1953, ASTMB, P70

[2]

DEJONG JGM, 1967, J APPL CHEM, V17, P246

[3] THE THERMAL DECOMPOSITION OF LITHIUM ALUMINIUM HYDRIDE [J].

GARNER, WE ;

HAYCOCK, EW .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1952, 211 (1106) :335-351

[4] The thermal decomposition of sodium and potassium azides. [J].

Garner, WE ;

Marke, DJB .

JOURNAL OF THE CHEMICAL SOCIETY, 1936, :657-664

[5]

GIBB JG, 1953, J APPL CHEM, V3, P213

[6]

KANTRO DL, 1966, S STRUCTURE PORTLAND, P309

[7]

KAWADA N, 1967, ZEM-KALK-GIPS, V20, P65

[8]

Kondo R., 1968, SEMENTO GIJUTSU NENP, V22, P73

[9]

Kondo R., 1968, 5 INT S CHEM CEM, P205

[10]

UEDA S, 1968, SEMENTO GIJUTSU NENP, V22, P67

← 1 →