Crystal structure of 4-{[(2,4-dihydroxybenzylidene) amino] methyl} cyclohexanecarboxylic acid

被引:1
作者
Danish, Muhammad [1 ]
Akbar, Saba [1 ]
Tahir, Muhammad Nawaz [2 ]
Butt, Rabia Ayub [1 ]
Ashfaq, Muhammad [1 ]
机构
[1] Univ Gujrat, Inst Nat Sci, Dept Chem, Gujarat 50700, Pakistan
[2] Univ Sargodha, Dept Phys, Sargodha, Pakistan
关键词
crystal structure; Schiff base; benzaldehyde; hydrogen bonding;
D O I
10.1107/S2056989015022343
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, C15H19NO4, the cyclo-hexyl ring adopts a chair conformation with both exocyclic C-C bonds in equatorial orientations. The dihedral angle between the basal plane of cyclo-hexyl ring and the 2,4-di-hydroxy-benzaldehyde moiety is 84.13(13). An intra-molecular O-H?N hydrogen bonds closes an S(6) ring. In the crystal, O-c-H center dot center dot center dot O-p (c = carb-oxy-lic acid, p = phenol) hydrogen bonds link the mol-ecules into [100] C(13) chains whereas an Op-H center dot center dot center dot O-c hydrogen bond generates [101] C(15) chains. Together, these bonds generate (010) sheets incorporating R-2(2)(20) loops. Weak C-H center dot center dot center dot O and C-H center dot center dot center dot pi inter-actions also occur.
引用
收藏
页码:O995 / U941
页数:8
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