DYNAMIC PROPERTIES OF FAST-ION-CONDUCTING BORATE GLASSES

被引：22
|
作者：
BALKANSKI, M [1 ]
WALLIS, RF [1 ]
DEPPE, J [1 ]
MASSOT, M [1 ]
机构：
[1] UNIV PARIS 06,PHYS SOLIDES LAB,F-75252 PARIS 05,FRANCE
来源：
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY | 1992年 / 12卷 / 03期
关键词：
D O I：
10.1016/0921-5107(92)90300-X
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The effect of adding modifiers and dopants on the structural and conducting properties of fast ion conducting borate glasses is studied, experimentally with the aid of Raman and infrared spectroscopy, and theoretically using network dynamics and lattice dynamics calculations. In particular, the effects of Li2O as a modifier, and LiX (X = F, Cl, Br, I) and Li2SO4 as a dopant are discussed. The modifier is found to change the structure of the glass matrix through which the lithium ions, supplied by the dopant, must diffuse. These structural modifications are analyzed and discussed in reference to their effect on the resulting ionic conductivity.
引用
收藏
页码：281 / 298
页数：18
相关论文
共 50 条
  • [1] Structure of fast-ion-conducting AgI-doped borate glasses in bulk and thin film forms
    Varsamis, CP
    Kamitsos, EI
    Chryssikos, GD
    PHYSICAL REVIEW B, 1999, 60 (06) : 3885 - 3898
  • [2] Structure of fast-ion-conducting lithium and sodium borate glasses by neutron diffraction and reverse Monte Carlo simulations
    Swenson, J
    Borjesson, L
    Howells, WS
    PHYSICAL REVIEW B, 1998, 57 (21): : 13514 - 13526
  • [3] Elastic properties of fast ion conducting lithium based borate glasses
    Gowda, VCV
    Anavekar, RV
    Rao, KJ
    JOURNAL OF NON-CRYSTALLINE SOLIDS, 2005, 351 (43-45) : 3421 - 3429
  • [4] Structure and conductivity of fast ion-conducting borate glasses
    Chalmers Univ of Technology, Goteborg, Sweden
    Phys B Condens Matter, (386-387):
  • [5] Structure and conductivity of fast ion-conducting borate glasses
    Swenson, J
    Borjesson, L
    McGreevy, RL
    Howells, WS
    PHYSICA B, 1997, 234 : 386 - 387
  • [6] Electrical properties of fast ion conducting silver based borate glasses: Application in solid battery
    Masoud, Emad M.
    Khairy, M.
    Mousa, M. A.
    JOURNAL OF ALLOYS AND COMPOUNDS, 2013, 569 : 150 - 155
  • [7] Structure of silver iodide/silver selenate fast-ion-conducting glasses: neutron diffraction experiments
    Cramer, C
    Price, DL
    Saboungi, ML
    JOURNAL OF PHYSICS-CONDENSED MATTER, 1998, 10 (28) : 6229 - 6242
  • [8] NMR spin-lattice relaxation and ionic conductivity in lithium thioborogermanate fast-ion-conducting glasses
    Meyer, B
    Borsa, F
    Martin, DM
    Martin, SW
    PHYSICAL REVIEW B, 2005, 72 (14):
  • [9] Ionic conductivity and relaxation dynamics in fast ion conducting silver borate glasses
    Bhattacharya, S
    Ghosh, A
    DEFECTS AND DIFFUSION IN HALIDES AND ICE - 7-YEAR RETROSPECTIVE, 2004, 229 : 29 - 41
  • [10] Correlation Between I-Ag Distance and Ionic Conductivity in AgI Fast-Ion-Conducting Glasses
    Sanson, A.
    Rocca, F.
    Armellini, C.
    Dalba, G.
    Fornasini, P.
    Grisenti, R.
    PHYSICAL REVIEW LETTERS, 2008, 101 (15)
12345