TANDEM ADDITION REDUCTION .22. 4-ALKENYL-1-METHOXY-1,4-CYCLOHEXADIENES BY TANDEM ADDITION MULTISTEP REDUCTION OF ALKENYL ALDEHYDES AND KETONES - SYNTHESIS OF 4-ALKENYL-3-CYCLOHEXEN-1-ONES BY SUBSEQUENT HYDROLYSIS

被引：5

作者：

FLISAK, JR ^{[1
]}

HALL, SS ^{[1
]}

机构：

[1] RUTGERS STATE UNIV,DEPT CHEM,NEWARK,NJ 07102

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1990年 / 112卷 / 20期

关键词：

D O I：

10.1021/ja00176a033

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of 4-alkenyl-1-methoxy-1,4-cyclohexadienes were prepared by a tandem addition-multistep reduction procedure. This one-pot process included the addition of 4-methoxyphenyllithium to alkenyl aldehydes and ketones, followed by multistep reduction of the intermediate benzyl alkoxides with lithium-ammonia-alcohol. Subsequent acid hydrolysis, selectively afforded the corresponding 4-alkenyl-3-cyclohexen-1-ones. © 1990, American Chemical Society. All rights reserved.

引用

页码：7299 / 7305

页数：7

共 7 条

[1] REDUCTION BY DISSOLVING METALS .6. SOME APPLICATIONS IN SYNTHESIS [J].