STUDIES OF THE HYDROGEN EVOLUTION REACTION ON LANTHANUM PHOSPHATE-BONDED COMPOSITE NICKEL-RUTHENIUM ELECTRODES IN 1-M ALKALINE-SOLUTIONS

被引：0

作者：

DUMONT, H ^{[1
]}

LOS, P ^{[1
]}

LASIA, A ^{[1
]}

MENARD, H ^{[1
]}

BROSSARD, L ^{[1
]}

机构：

[1] INST RECH HYDRO QUEBEC,VARENNES J3X 1S1,PQ,CANADA

来源：

JOURNAL OF APPLIED ELECTROCHEMISTRY | 1993年 / 23卷 / 07期

关键词：

D O I：

暂无

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The electrocatalytic properties of lanthanum phosphate-bonded composite nickel-ruthenium electrodes for the hydrogen and oxygen evolution reactions were studied in 1 M KOH at 25-degrees-C. Ruthenium was chemically deposited on nickel powder particles prior to polymerization of Ni/Ru powder with lanthanum phosphate. X-ray diffraction (XRD), X-ray fluorescence (XRF), BET, differential thermal analysis (DTA), scanning electron microscopy (SEM), EDX and u.v./vis. spectrophotometry were used to investigate the composition, morphology and characteristics of the electrodes. The influence of the ruthenium content and polymerization temperature on the electrocatalytic activity for hydrogen and oxygen evolution were studied. The mechanism and kinetics of the hydrogen evolution reaction (HER) were investigated using both steady-state polarization and a.c. impedance techniques.

引用

页码：684 / 692

页数：9

共 33 条

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