NEW COMPLEXES OF TITANIUM WITH BIS(TRIMETHYLSILYL)AMIDO LIGANDS

被引：19

作者：

BAI, Y

ROESKY, HW

NOLTEMEYER, M

机构：

[1] Inst. F. Anorg. Chemie, D. Univ., Göttingen, W-3400

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1991年 / 595卷 / 04期

关键词：

TITANIUM COMPLEX COMPOUNDS; CYCLOPENTADIENYL TITANIUM BIS(TRIMETHYLSILYL)AMIDO COMPOUNDS; SYNTHESES; CRYSTAL STRUCTURE;

D O I：

10.1002/zaac.19915950104

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of cp'TiCl3 with LiN(SiMe3)2.Et2O 1 yield the compounds cp'TiCl2N(SiMe3)2 (cp' = C5H5 2, C5H4SiMe3 3, C5H3(SiMe3)2 4, C5Me5 5) and cp'TiCl[N(SiMe3)2]2 (cp' = C5H5 6). Compound 2 was characterized by an X-ray structural analysis with space group P2(1)/n and unit cell dimensions of a = 1660.9(7), b = 688.6(3), c = 1739.1(8) pm and beta = 117.18(3)-degrees.

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页码：21 / 26

页数：6

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