LIFETIME OF THE BOND NETWORK AND GEL-LIKE ANOMALIES IN SUPERCOOLED WATER

被引：147

作者：

SCIORTINO, F ^{[1
]}

POOLE, PH ^{[1
]}

STANLEY, HE ^{[1
]}

HAVLIN, S ^{[1
]}

机构：

[1] BOSTON UNIV,DEPT PHYS,BOSTON,MA 02215

来源：

PHYSICAL REVIEW LETTERS | 1990年 / 64卷 / 14期

关键词：

D O I：

10.1103/PhysRevLett.64.1686

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

We analyze the distribution of bond lifetimes in simulations of liquid water using a novel bond definition. We find that the characteristic lifetimes of the bonds and of the gel network itself both increase strongly when temperature is decreased"and even appear to diverge at a temperature well below the freezing temperature"thereby providing an appealing physical picture of the anomalous behavior of water in the supercooled region. © 1990 The American Physical Society.

引用

页码：1686 / 1689

页数：4

共 24 条

[1]

ANGELL CA, 1981, WATER COMPREHENSIVE, V7

[2]

[Anonymous], 2005, STRUCTURE PROPERTIES

[3] DIFFUSION EFFECTS OF HYDROGEN-BOND FLUCTUATIONS .2. FROM THE SHORT TO THE LONG-TIME REGIME IN THE TRANSLATIONAL DYNAMICS OF WATER [J].