USE OF IN SITU MOSSBAUER-SPECTROSCOPY FOR ELECTROCHEMICAL REACTIONS INVOLVING FE-57

被引：1

作者：

FOURNES, L

GRENIER, JC

CHANSON, C

BEZDICKA, P

WATTIAUX, A

POUCHARD, M

机构：

[1] SAFT, DEPT ACCUMULATEURS, F-33074 BORDEAUX, FRANCE

[2] SLOVAK ACAD SCI, CTR CHEM RES, INST INORGAN CHEM, CS-84236 BRATISLAVA, CZECHOSLOVAKIA

来源：

HYPERFINE INTERACTIONS | 1990年 / 57卷 / 1-4期

关键词：

D O I：

10.1007/BF02405729

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

An electrochemical cell and relevant electrodes have been carried out in order to study in situ various electrochemical reactions involving iron using57Fe Mössbauer resonance. The electrochemical behaviour of iron in strongly alkaline solution (KOH 5N) in the potential range (-1200<E<-200 mV) has been examined. The introduction of sulfide ions in this electrolyte leads to the formation of a new phase, the mackinawite FeS. Optimized electrochemical conditions for growing a FeS deposit on an iron electrode have been specified. © 1990 J.C. Baltzer A.G. Scientific Publishing Company.

引用

页码：1829 / 1832

页数：4

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