A ROUTE TO ETA(2)-ALKYNE COMPLEXES OF VANADIUM(I) - CRYSTAL-STRUCTURE OF TRANS-[IV(CO)(2)(PME(2)PH)(2)(2-BUTYNE)]

被引：12

作者：

GAILUS, H ^{[1
]}

MAELGER, H ^{[1
]}

REHDER, D ^{[1
]}

机构：

[1] UNIV HAMBURG,INST ANORGAN & ANGEW CHEM,D-20146 HAMBURG,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 465卷 / 1-2期

关键词：

VANADIUM; ALKYNE; CRYSTAL STRUCTURE;

D O I：

10.1016/0022-328X(94)87053-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction between [V(CO)(6)](-), halogens, phosphines and alkynes yields the complexes trans-[HaIV(CO)(2)(PR(3))(2)(alkyne)], which have been characterized by IR and multinuclear NMR spectroscopy. The structure of the title compound has been determined by a single crystal X-diffraction study.

引用

页码：181 / 185

页数：5

共 50 条

[21] Crystal structure of 1,4-bis(triphenylstannyl)-2-butyne, Ph3SnCH2CCCH2SnPh3
Jurkschat, K
Schürmann, M
Schulte, M
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 1999, 214 (04): : 471 - 472
[22] TRANS,TRANS-[NI-2(CN)(4)(ME(2)PCH(2)PME(2))(2)]
MANOJLOVICMUIR, L
MUIR, KW
RENNIE, MA
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1995, 51 : 1533 - 1535
[23] TANTALUM(I) ALKYNE COMPLEXES - TA(CO)2(ETA-2-RC=CR)(I)L2
MCGEARY, MJ
GAMBLE, AS
TEMPLETON, JL
ORGANOMETALLICS, 1988, 7 (02) : 271 - 279
[24] TRIMETHYLPHOSPHINE AS A REACTIVE SOLVENT - SYNTHESIS AND CRYSTAL-STRUCTURE OF TA(PME3)3(ETA-2-CH2-PME2)(ETA-2-CH-PME2) AND SYNTHESIS OF RELATED MOLYBDENUM AND TUNGSTEN COMPOUNDS
GIBSON, VC
GREBENIK, PD
GREEN, MLH
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (19) : 1101 - 1102
[25] PREPARATION AND PROPERTIES OF MOLYBDENUM AND TUNGSTEN DINITROGEN COMPLEXES .42. PREPARATION AND CHARACTERIZATION OF W(V) DIAZOALKANE COMPLEXES MER,TRANS-[WX(3)(NN=CMER)(PME(2)PH)(2)](X=BR,IR=ME,PH) AND HYDRAZIDO(2-) COMPLEX [WT,(NNH2)(PME(2)PH)(2)] - X-RAY STRUCTURE OF MER,TRANS-[WBR3(NN=CMEPH)(PME(2)PH)(2)]
OSHITA, H
MIZOBE, Y
HIDAI, M
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 461 (1-2) : 43 - 49
[26] REACTIONS OF [WI2(CO)(NCME)(ETA-2-MEC2ME)2], [WIZ(CO)(NCME)(ETA-2-PHCZPH)2] WITH CARBON-MONOXIDE TO GIVE EITHER [WI2(CO)2(ETA-2-MEC2ME)2] OR [W(MU-I)I(CO)(ETA-2-PHC2PH)2]2 - CRYSTAL-STRUCTURE OF [WI2(CO)2(ETA-2-MEC2ME)2]
ARMSTRONG, EM
BAKER, PK
DREW, MGB
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 336 (03) : 377 - 383
[27] PREPARATION OF SOME NEW COMPLEXES OF TYPE TRANS-[IRX(CO)L2] (L=PME3 PET3 PME2PH OR ASME2PH)
DEEMING, AJ
SHAW, BL
JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1968, (08): : 1887 - &
[28] REACTIVITY OF HYDRIDOCARBONYLVANADIUM COMPLEXES - SYNTHESIS AND CHARACTERIZATION OF ALKYLVANADIUM COMPLEXES AND THE MOLECULAR-STRUCTURE OF TRANS-[V(CO)2(PH2PCH2CH2PPH2)2]
REHDER, D
SUSSMILCH, F
PRIEBSCH, W
FORNALCZYK, M
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 411 (03) : 357 - 367
[29] PROTONATION OF TRANS-[MO(ETA(2)-MECCH)(2)(PH(2)PCH(2)CH(2)PPH(2))(2)] - MECHANISM OF FORMATION OF TRANS-[MOX(CHCHME)(PH(2)PCH(2)CH(2)PPH(2))(2)] (X=CL OR BR) OR TRANS-[MOF(CCH(2)ME)(PH(2)PCH(2)CH(2)PPH(2))(2)]
HENDERSON, RA
OGLIEVE, KE
SALISBURY, P
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1995, (15): : 2479 - 2487
[30] SYNTHESIS AND REDOX PROPERTIES OF COMPLEXES OF RHENIUM(I) WITH CYANOGUANIDINE AND SOME DERIVATIVES - CRYSTAL-STRUCTURE OF TRANS-[RE(NCNC(NH2)2)(CNME)(PH2PCH2CH2PPH2)2][BF4]
FERNANDA, M
CARVALHO, NN
POMBEIRO, AJL
HILLS, A
HUGHES, DL
RICHARDS, RL
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 469 (02) : 179 - 187

← 1 2 3 4 5 →