A ROUTE TO ETA(2)-ALKYNE COMPLEXES OF VANADIUM(I) - CRYSTAL-STRUCTURE OF TRANS-[IV(CO)(2)(PME(2)PH)(2)(2-BUTYNE)]

被引：12

作者：

GAILUS, H ^{[1
]}

MAELGER, H ^{[1
]}

REHDER, D ^{[1
]}

机构：

[1] UNIV HAMBURG,INST ANORGAN & ANGEW CHEM,D-20146 HAMBURG,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 465卷 / 1-2期

关键词：

VANADIUM; ALKYNE; CRYSTAL STRUCTURE;

D O I：

10.1016/0022-328X(94)87053-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction between [V(CO)(6)](-), halogens, phosphines and alkynes yields the complexes trans-[HaIV(CO)(2)(PR(3))(2)(alkyne)], which have been characterized by IR and multinuclear NMR spectroscopy. The structure of the title compound has been determined by a single crystal X-diffraction study.

引用

页码：181 / 185

页数：5

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