KINETIC-STUDIES ON THE COBALT(II) NAPHTHENATE CATALYZED DECOMPOSITION OF CUMENE HYDROPEROXIDE IN BENZENE

被引:4
作者
SAWADA, H [1 ]
ISHIGAKI, H [1 ]
KATO, M [1 ]
NAKAYAMA, M [1 ]
机构
[1] NIPPON OIL & FATS CO LTD, CHEM & EXPLOSIVES RES LAB, TAKETOYO, AICHI 47023, JAPAN
关键词
D O I
10.1246/bcsj.64.785
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The cobalt(II) naphthenate[Co(Nap)2] catalyzed decomposition of cumene hydroperoxide(CHP) gave a mixture of alpha-cumyl alcohol, acetophenone and di-alpha-cumyl peroxide in benzene at 25-degrees-C. All experimentally observed time courses of disappearing CHP and an increasing of three products compared well with theoretical values.
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页码:785 / 788
页数:4
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