REGIOSPECIFIC REACTIONS OF OMEGA-CARBOXY-ALPHA-AMINO ACIDS USING ASPARTIC-ACID

被引：0
作者：
BURGER, VK
GOLD, M
NEUHAUSER, H
RUDOLPH, M
机构：
来源：
CHEMIKER-ZEITUNG | 1991年 / 115卷 / 03期
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Regiospecific syntheses of alpha- and beta-carboxylic acid derivatives as well as of unsymmetrically substituted alpha, beta-dicarboxylic acid derivatives of aspartic acid can be achieved via intermediates 2 and 3. Compound 2 is obtained in high yield on reaction of aspartic acid with hexafluoroacetone, compound 3 on reaction of 2 with thionyl chloride.
引用
收藏
页码：77 / 82
页数：6
相关论文
共 46 条
[1]   SUICIDE ENZYME INACTIVATORS [J].
ABELES, RH ;
MAYCOCK, AL .
ACCOUNTS OF CHEMICAL RESEARCH, 1976, 9 (09) :313-319
[2]  
BURGER K, 1990, CHEM ZTG, V114, P251
[3]  
BURGER K, 1979, LIEBIGS ANN CHEM, P1547
[4]  
BURGER K, 1990, CHEM ZTG, V114, P249
[5]  
BURGER K, CHEM ZTG
[6]  
BURGER K, 1965, VERSUCHE
[7]  
BURGER K, 1965, THESIS TH MUNCHEN
[8]  
CAMPBELL MM, 1979, COMPREHENSIVE ORGANI, V4, P1033
[9]   POLYPEPTIDES .3. SYNTHESIS OF C-TERMINAL TETRAPEPTIDE SEQUENCE OF GASTRIN ITS OPTICAL ISOMERS AND ACYLATED DERIVATIVES [J].
DAVEY, JM ;
LAIRD, AH ;
MORLEY, JS .
JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1966, (05) :555-&
[10]   The constitution of " thiocyanates " containing an elecotronegative group [J].
Dixon, AE ;
Taylor, J .
JOURNAL OF THE CHEMICAL SOCIETY, 1908, 93 :684-700
12345