POLYHYDROXY ALCOHOLS AS HYDROGEN DONORS IN CATALYTIC TRANSFER REDUCTION OF CARBONYL GROUPS OVER MGO

被引：8

作者：

KIJENSKI, J

RUSZCZYNSKI, J

KNEDLER, I

GLINSKI, M

机构：

[1] Chemical Faculty, Laboratory of Catalytic Synthesis, Warsaw Technical University (Politechnika), Warsaw, 00-662

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 1993年 / 49卷 / 02期

关键词：

D O I：

10.1007/BF02067693

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The catalytic transfer reduction of benzaldehyde with polyhydric alcohols has been studied over MgO. 1,3-Propanediol, 1,4-butanediol, 1,6-hexanediol, 1,2,6-hexanetriol and triethylene glycol were found to be effective reductants for the carbonyl group. Vicinal diols such as 1,2-ethanediol and 1,2-propanediol did not exhibit any activity in the transformation studied. 1,4-Butanediol was successfully used in the large laboratory scale CTR of benzaldehyde.

引用

页码：287 / 291

页数：5

共 4 条

[1] REDUCTION OF ALKYL ALKYL, ARYL ALKYL AND CYCLIC-KETONES BY CATALYTIC HYDROGEN TRANSFER OVER MAGNESIUM-OXIDE [J].

KIJENSKI, J ;

GLINSKI, M ;

CZARNECKI, J .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1991, (11) :1695-1698

[2] INFLUENCE OF SODIUM ON PHYSICOCHEMICAL AND CATALYTIC PROPERTIES OF MAGNESIUM-OXIDE [J].

KIJENSKI, J ;

MALINOWSKI, S .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1978, 74 :250-261

[3]

KIJENSKI J, 1989, HETEROGENEOUS CATALY, V41, P231

[4]

KIJENSKI J, 1991, HETEROGENEOUS CATALY, V2, P169

← 1 →