CRYSTAL-STRUCTURE OF [SNCL4(PH(2)PCH(2)-CH(2)PPH(2))]CENTER-DOT-CH2CL2

被引：0

作者：

KUNKEL, F

DEHNICKE, K

机构：

[1] UNIV MARBURG,FACHBEREICH CHEM,D-35032 MARBURG,GERMANY

[2] UNIV KARLSRUHE,INST ANORGAN CHEM,D-76128 KARLSBURG,GERMANY

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1995年 / 50卷 / 05期

关键词：

CRYSTAL STRUCTURE; CHELATE LIGANDS; 1,2-BIS(DIPHENYLPHOSPHINE)ETHANE;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[SnCl4(Ph(2)PCH(2)-CH(2)PPh(2))]. CH2Cl2 has been characterized by a crystal structure determination. Space group P2(1)/c, Z = 4, 5565 observed unique reflections with I > 2 sigma(I), R = 0.043. Lattice dimensions at -70 degrees C: a = 1141.4(6), b = 2178.3(11), c = 1399.1(7) pm, beta = 108.96(3)degrees. The complex forms monomeric molecules with the 1,2-bis(diphenylphosphino)ethane as chelating ligand. Bond lengths (average): Sn-P 266.7 pm, Sn-Cl 241.8 pm.

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页码：848 / 850

页数：3

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