PREPARATION AND STRUCTURE OF SILACYCLOHEPTATRIENE

被引：37
作者：
NAKADAIRA, Y [1 ]
SATO, R [1 ]
SAKURAI, H [1 ]
机构：
[1] TOHOKU UNIV,FAC SCI,DEPT CHEM,SENDAI,MIYAGI 980,JAPAN
来源：
ORGANOMETALLICS | 1991年 / 10卷 / 02期
关键词：
D O I：
10.1021/om00048a020
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The first preparation of C-unsubstituted silacycloheptatrienes, silicon analogues of cycloheptatriene, is described along with spectroscopic properties. A 2,5-diphenyl derivative has been similarly prepared. The new and general preparative method for silacycloheptatriene is based on the reaction of the silacyclohexadienyl anion with chlorocarbene. The reaction pathway to silacycloheptatriene has been examined by the use of deuterium labeling.
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页码：435 / 442
页数：8
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