MAKING AND BREAKING OF SI-E (E=C, SI) BONDS BY OXIDATIVE ADDITION AND REDUCTIVE ELIMINATION-REACTIONS

被引：78
作者：
SCHUBERT, U
机构：
[1] Institut für Anorganische Chemie der Universität, Würzburg, D-97074, Am Hubland
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 04期
关键词：
D O I：
10.1002/anie.199404191
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Important steps in metal‐mediated stoichiometric or catalytic reactions of organosilicon compounds are oxidative additions and reductive eliminations. Although the tools to tune the ability of a metal complex fragment to undergo such reactions are, in principle, known—for example, oxidative additions are facilitated by metals which are easily oxidized and by small ancillary ligands—the challenge for the chemist is to make these reactions, particularly for SiC and SiSi bonds, more predictable. Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany
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页码：419 / 421
页数：3
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