ETARD REACTION .6. OXIDATION OF CIS AND TRANS-DECALINE WITH CHROMYL CHLORIDE

被引：19
作者：
RENTEA, CN
RENTEA, M
NECSOIU, I
NENITZES.CD
机构：
[1] Institute of Organic Chemistry, the Academy of S.R., Bucharest, Rumania
来源：
TETRAHEDRON | 1968年 / 24卷 / 13期
关键词：
D O I：
10.1016/S0040-4020(01)98663-6
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Oxidation of trans-decaline with chromyl chloride yielded a mixture containing a small amount of trans-9-decalol and several ketones among which spiro [4.5]decan-6-one, trans-1-decalone, cis-1-decalone, 9,10-octal-1-one and 1-tetralone were identified. The main reaction product, spiro[4.5]-decan-6-one, for the first time is reported to appear among the products of decaline oxidation. Oxidation of cis-decaline with chromyl chloride yielded cis-9-decalol and a mixture of the same ketones as above, but in a slightly different ratio. The reaction mechanisms are discussed. © 1968.
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页码：4667 / &
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