SYNDIOTACTIC POLY(1-OXO-2-PHENYLTRIMETHYLENE) - ON THE MODE OF THE CHAIN GROWTH UNDER PALLADIUM CATALYSIS

被引：131

作者：

BARSACCHI, M

CONSIGLIO, G

MEDICI, L

PETRUCCI, G

SUTER, UW

机构：

[1] SWISS FED INST TECHNOL,TECH CHEM LAB,UNIV STR 6,CH-8092 ZURICH,SWITZERLAND

[2] SWISS FED INST TECHNOL,INST POLYMERE,CH-8092 ZURICH,SWITZERLAND

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 08期

关键词：

D O I：

10.1002/anie.199109891

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Selection between the enantiotopic faces of an olefin occurs in the sterically controlled carbonylation of styrene with [Pd(phen)(p-CH3C6H4SO3)2] as catalyst to give the title compound 1. The identification of the polymer end groups and the parallel reactions with other catalytic systems shed light on the mechanism of the reaction.

引用

页码：989 / 991

页数：3

共 19 条

[1] CATIONIC ETA-3-ALLYL COMPLEXES .16. ISOTACTIC OLIGOMERIZATION OF STYRENE IN THE PRESENCE OF A HOMOGENEOUS NICKEL(II) CATALYST [J].