ON THE USE OF LINEAR VARIATION BASIS FUNCTIONS THAT DO NOT SATISFY THE BOUNDARY-CONDITIONS

被引:43
作者
GOODFRIEND, PL
机构
[1] Department of Chemistry, University of Maine, Orono
关键词
Basis functions - Coulomb field - Harmonic oscillators - Hydrogen atoms - Linear variation;
D O I
10.1088/0953-4075/23/9/009
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
A method for using basis functions that do not satisfy the boundary conditions in linear variation functions is presented and applied to the problems of a hydrogen atom at the centre of an infinitely strong sphere, an electron in a Coulomb field outside an impenetrable sphere and a harmonic oscillator in a one-dimensional box. © 1990 IOP Publishing Ltd.
引用
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页码:1373 / 1379
页数:7
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