THEORETICAL BEHAVIOR OF CONCENTRATION CELLS BASED ON ABO(3) PEROVSKITE MATERIALS WITH PROTONIC AND OXYGEN-ION CONDUCTION

被引：72
作者：
FRADE, JR
机构：
[1] Ceramics and Glass Engineering Department, University of Aveiro
来源：
SOLID STATE IONICS | 1995年 / 78卷 / 1-2期
关键词：
CONCENTRATION CELLS; SENSORS; IONIC CONDUCTIVITY; PROTON; PEROVSKITES; TRANSPORT NUMBERS;
D O I：
10.1016/0167-2738(95)00008-T
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
An equivalent circuit for open circuit conditions was derived to describe the transport properties of ABO(3) perovskite materials with protonic, oxygen ion and electronic conduction when the composition of the atmosphere is a variable. The open circuit model can be used for interpreting the results of concentration cells, which might be useful to study the relevant material properties of this type of materials. This model is also used to discuss the basic features and limitations of potentiometric gas sensors based on this type of materials.
引用
收藏
页码：87 / 97
页数：11
相关论文
共 27 条
[1]   IONIC-CONDUCTIVITY OF GADOLINIUM-DOPED BARIUM CERATE PEROVSKITES [J].
BONANOS, N ;
ELLIS, B ;
KNIGHT, KS ;
MAHMOOD, MN .
SOLID STATE IONICS, 1989, 35 (1-2) :179-188
[2]   TRANSPORT-PROPERTIES AND CONDUCTION MECHANISM IN HIGH-TEMPERATURE PROTONIC CONDUCTORS [J].
BONANOS, N .
SOLID STATE IONICS, 1992, 53 :967-974
[3]   INVESTIGATIONS ON BATH0.9GD0.1O3 AS AN INTERMEDIATE TEMPERATURE FUEL-CELL SOLID ELECTROLYTE [J].
COOK, RL ;
OSBORNE, JJ ;
WHITE, JH ;
MACDUFF, RC ;
SAMMELLS, AF .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1992, 139 (02) :L19-L20
[4]   PROTON CONDUCTIVITY IN STRONTIUM CERATES FOR HYDROGEN GAS SENSORS IN COAL-GASIFICATION SYSTEMS [J].
DESCHUTTER, F ;
VANGRUNDERBEEK, J ;
LUYTEN, J ;
KOSACKI, I ;
VANLANDSCHOOT, R ;
SCHRAM, J ;
SCHOONMAN, J .
SOLID STATE IONICS, 1992, 57 (1-2) :77-81
[5]   EVALUATION OF PROTON CONDUCTIVITY IN SRCEO3, BACEO3, CAZRO3 AND SRZRO3 BY TEMPERATURE PROGRAMMED DESORPTION METHOD [J].
HIBINO, T ;
MIZUTANI, K ;
YAJIMA, T ;
IWAHARA, H .
SOLID STATE IONICS, 1992, 57 (3-4) :303-306
[6]  
Hoar T. P., 1938, T FARADAY SOC, V34, P867
[7]   PROTONIC CONDUCTION IN THE SINGLE-CRYSTALS OF Y-DOPED SRZRO3 [J].
HUANG, HH ;
ISHIGAME, M ;
SHIN, S .
SOLID STATE IONICS, 1991, 47 (3-4) :251-255
[8]   OXIDE-IONIC AND PROTONIC CONDUCTORS BASED ON PEROVSKITE-TYPE OXIDES AND THEIR POSSIBLE APPLICATIONS [J].
IWAHARA, H .
SOLID STATE IONICS, 1992, 52 (1-3) :99-104
[9]   NERNSTIAN HYDROGEN SENSOR USING BACEO3-BASED, PROTON-CONDUCTING CERAMICS OPERATIVE AT 200-DEGREES-C-900-DEGREES-C [J].
IWAHARA, H ;
UCHIDA, H ;
OGAKI, K ;
NAGATO, H .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1991, 138 (01) :295-299
[10]   PROTONIC CONDUCTION IN CALCIUM, STRONTIUM AND BARIUM ZIRCONATES [J].
IWAHARA, H ;
YAJIMA, T ;
HIBINO, T ;
OZAKI, K ;
SUZUKI, H .
SOLID STATE IONICS, 1993, 61 (1-3) :65-69
123