SECONDARY MINIMUM ANALYSIS IN THE DLVO-THEORY

被引:12
|
作者
FORNES, JA
机构
[1] Univ Federal de Goias, Inst de, Matematica e Fisica, Goiania, Braz, Univ Federal de Goias, Inst de Matematica e Fisica, Goiania, Braz
关键词
COLLOID CHEMISTRY - Mathematical Models - SURFACE PHENOMENA;
D O I
10.1007/BF01410994
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
One of the characteristics features of the DLVO (Derjaguin-Landau-Verwey-Overbeek) theory is the presence of a secondary minimum in the curves of potential energy versus the interacting surfaces' distance. A simple method for determining the secondary minimum distance and energy for two parallel plane surfaces interacting with constant potential and constant surface charge density in a symmetrical electrolyte solution is presented. Both cases are treated, namely, non-retarded and retarded interaction. Two graphics which provide a quick survey for determining the secondary minimum are reported.
引用
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页码:1004 / 1007
页数:4
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