DIPOLE-MOMENTS OF SOME PHENYL AND CHLOROPHENYL PHOSPHORUS-HALOGEN COMPOUNDS

被引：1

作者：

WANG, CG ^{[1
]}

BOCK, E ^{[1
]}

PEELING, J ^{[1
]}

JANZEN, AF ^{[1
]}

机构：

[1] UNIV MANITOBA,DEPT CHEM,WINNIPEG R3T 2N2,MANITOBA,CANADA

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1991年 / 57卷 / 1-2期

基金：

加拿大自然科学与工程研究理事会;

关键词：

MOLECULAR ELECTRIC DIPOLE MOMENTS; PHENYLPHOSPHORUS HALOGEN COMPOUNDS;

D O I：

10.1080/10426509108038840

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The electric dipole moments of o-C1C6H4PC12 1, C6H5PF4 2, o-CIC6H4PF4 3, C6H5P (0) F, 4, C6H5P (O) HF 5. C6H5P (O) H (OH) 6, and o-CI6H4P (O) CI2 7, were determined in dilute benzene solution at 25°C. The phosphoryl bond moment P=O in compounds 4, 5, and 7 was estimated using simple bondadditivity calculations. The results obtained were 4.55D, 3.64D, and 5.52D for compounds 4, 5, and 7. respectively. Dipole moments for compounds 2 and 3 were also calculated theoretically using INDO MO techniques. The calculated values differed from the experimental values by about 12%. © 1991 Taylor & Francis Group, LLC. All rights reserved.

引用

页码：123 / 125

页数：3

共 50 条

[21] DIPOLE-MOMENTS OF SOME DIARYL DISULFIDES
PAPPALARDO, GC
PISTARA, S
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1972, 17 (01): : 2 - +
[22] DIPOLE-MOMENTS OF SOME MOLECULES IN SOLUTION
VIJ, JK
SINGH, B
RAO, VVR
INDIAN JOURNAL OF PHYSICS AND PROCEEDINGS OF THE INDIAN ASSOCIATION FOR THE CULTIVATION OF SCIENCE, 1973, 47 (09): : 533 - 538
[23] THE DIPOLE-MOMENTS OF SOME CHLOROPENTANES AND BROMOPENTANES
BERBERIAN, JG
JOURNAL OF CHEMICAL PHYSICS, 1983, 78 (08): : 5269 - 5270
[24] DIPOLE-MOMENTS OF SOME STYRENE COPOLYMERS
KUCUKYAVUZ, Z
BAYSAL, BM
MACROMOLECULES, 1988, 21 (07) : 2287 - 2291
[25] DIPOLE-MOMENTS OF SOME ISOMERIC ETHYLPHENOLS
BAHADUR, B
YADAV, RA
CURRENT SCIENCE, 1972, 41 (17): : 649 - &
[26] DIPOLE-MOMENTS OF SOME CHOLESTEROL DERIVATIVES
JADZYN, J
JADZYN, C
PASEK, K
ROCZNIKI CHEMII, 1977, 51 (12): : 2471 - 2475
[27] DIPOLE-MOMENTS OF SOME DIALKYL SULFOXIDES
PETKOVIC, DM
PAVLOVIC, MS
ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-FRANKFURT, 1974, 88 (1-4): : 54 - 58
[28] DIPOLE-MOMENTS OF SOME ISOXAZOLE DERIVATIVES
MAZHEIKA, IB
SOKOLOV, SD
YUDINTSE.IM
YANKOVSK.IS
KHIMIYA GETEROTSIKLICHESKIKH SOEDINENII, 1972, (04): : 460 - &
[29] DIPOLE-MOMENTS OF IODINE COMPOUNDS COMPLEXED WITH SOME ALIPHATIC-AMINES
TOYODA, K
IMAI, M
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1975, 48 (11) : 3393 - 3394
[30] DIPOLE-MOMENTS OF SUBSTITUTED ADAMANTANES AND CORRELATION OF DIPOLE-MOMENTS OF ALIPHATIC-COMPOUNDS WITH SUBSTITUENT CONSTANTS
DEADY, LW
KENDALL, M
JONES, RAY
TOPSOM, RD
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1973, (04): : 416 - 420

← 1 2 3 4 5 →