AN ADAMANTANE-LIKE [GE4TE10]4- ANION - SYNTHESIS AND SINGLE-CRYSTAL STRUCTURE DETERMINATION OF (ET4N)4[GE4TE10]

被引：15

作者：

DHINGRA, SS ^{[1
]}

HAUSHALTER, RC ^{[1
]}

机构：

[1] NEC CORP LTD,RES INST,4 INDEPENDENCE WAY,PRINCETON,NJ 08540

来源：

POLYHEDRON | 1994年 / 13卷 / 19期

关键词：

D O I：

10.1016/S0277-5387(00)83436-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The extraction of the alloy of composition K4Ge4Te10 in ethylenediamine (en) in the presence of Et4NBr afforded black cubic crystals of (Et4N)4[Ge4Te10], 1, in 72% yield. The X-ray diffraction data revealed two crystallographically independent [Ge4Te10]4-clusters each having approximate 43mBAR point symmetry. The Ge4+ based tetrahedra share three corners to form an adamantane-like (Ge4Te6) unit with the fourth site occupied by a terminal Te2- ligand.

引用

页码：2775 / 2779

页数：5

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