PREPARATION OF POLY(PARA-PHENYLENE VINYLENE) DEUTERIUM LABELED IN THE VINYLENE POSITIONS

被引：1

作者：

LIANG, WB

RICE, DM

KARASZ, FE

DENTON, FR

LAHTI, PM

机构：

[1] UNIV MASSACHUSETTS,DEPT POLYMER SCI & ENGN,AMHERST,MA 01003

[2] UNIV MASSACHUSETTS,DEPT CHEM,AMHERST,MA 01003

来源：

POLYMER | 1992年 / 33卷 / 08期

关键词：

POLY(PARA-PHENYLENE VINYLENE); SYNTHESIS; DEUTERIUM LABELING; CONDUCTING POLYMERS;

D O I：

10.1016/0032-3861(92)91084-F

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The preparation of poly(p-phenylene vinylene) specifically labelled at the vinylene positions is herein described. The extent of deuteration is estimated by i.r. spectroscopy, and the mechanism of hydrogen/deuterium exchange during the polymerization process is discussed.

引用

收藏

页码：1780 / 1782

页数：3

相关论文

共 16 条

[1] PRECURSOR-ROUTE POLY(P-PHENYLENEVINYLENE) - POLYMER CHARACTERIZATION AND CONTROL OF ELECTRONIC-PROPERTIES [J].

BRADLEY, DDC .

JOURNAL OF PHYSICS D-APPLIED PHYSICS, 1987, 20 (11) :1389-1410

[2] INFRARED CHARACTERIZATION OF ORIENTED POLY(PHENYLENE VINYLENE) [J].

BRADLEY, DDC ;

FRIEND, RH ;

LINDENBERGER, H ;

ROTH, S .

POLYMER, 1986, 27 (11) :1709-1713

[3] SOLID-STATE DEUTERIUM NMR-STUDIES OF POLY(P-PHENYLENE) AND TRANS-POLYACETYLENE AS A BLEND IN POLYSTYRENE [J].

DUMAIS, JJ ;

JELINSKI, LW ;

GALVIN, ME ;

DYBOWSKI, C ;

BROWN, CE ;

KOVACIC, P .

MACROMOLECULES, 1989, 22 (02) :612-617

[4]

GRANIER T, 1986, J POLYM SCI PP, V24, P2993

[5]

JELINSKI LW, 1985, ANNU REV MATER SCI, V15, P359

[6]

KAPLAN S, 1989, SYNTHETIC MET, V29, pE235, DOI 10.1016/0379-6779(89)90301-9

[7] POLYMERIZATION OF ALPHA,ALPHA'-BIS(DIALKYLSULFONIO)-PARA-XYLENE DIHALIDES VIA PARA-XYLYLENE INTERMEDIATES - EVIDENCE FOR A NONRADICAL MECHANISM [J].

LAHTI, PM ;

MODARELLI, DA ;

DENTON, FR ;

LENZ, RW ;

KARASZ, FE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (21) :7258-7259

[8] MOLECULAR-ORIENTATION OF HIGHLY DRAWN POLY(PARA-2-METHOXYPHENYLENE VINYLENE) [J].

LIANG, WB ;

KARASZ, FE .

POLYMER, 1991, 32 (13) :2363-2366

[9] SELECTION OF NON-PROTONATED CARBON RESONANCES IN SOLID-STATE NUCLEAR MAGNETIC-RESONANCE [J].

OPELLA, SJ ;

FREY, MH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (19) :5854-5856

[10]

SCHROTER B, 1981, MAKROMOL CHEM, V182, P3185