A SCHIFF-BASE DERIVED REDOX-RESPONSIVE RECEPTOR MOLECULE AND RELATED-COMPOUNDS WITH POTENTIAL AS NONLINEAR OPTICAL-MATERIALS

被引：45
作者：
BEER, PD
SIKANYIKA, H
机构：
[1] Department of Chemistry, University of Birmingham, Birmingham, B15 2TT
来源：
POLYHEDRON | 1990年 / 9卷 / 08期
关键词：
D O I：
10.1016/S0277-5387(00)81299-1
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new Schiff base redox-responsive receptor molecule (8) containing a ferrocene redox-active centre and a benzo-15-crown-5 metal cation binding unit is reported. The reversible redox couple of 8 shifts anodically on addition of Na+, K+ and Mg2+ guest cations. The synthesis and electrochemical properties of two related ferrocenyl Schiff base compounds (9 and 10) possessing electron-donor and -acceptor moieties which have potential as non-linear optical materials are also reported. © 1990.
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页码：1091 / 1094
页数：4
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