HOMOGENEOUS CATALYSIS IN WATER .2. SYNTHESIS AND CHARACTERIZATION OF RUTHENIUM WATER-SOLUBLE COMPLEXES

被引：54

作者：

FACHE, E

SANTINI, C

SENOCQ, F

BASSET, JM

机构：

[1] INST RECH CATALYSE,2 AV A EINSTEIN,F-69626 VILLEURBANNE,FRANCE

[2] ECOLE SUPER CHIM IND LYON,F-69100 VILLEURBANNE,FRANCE

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1992年 / 72卷 / 03期

关键词：

D O I：

10.1016/0304-5102(92)85010-D

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Seven water-soluble complexes of ruthenium and TPPTS have been prepared and characterized (TPPTS is the trisodium salt of the tri(m-sulfophenyl)phosphine): [RuCl2(TPPTS)2]2 1, RuHCl(TPPTS)3 2, RuH(OAc)(TPPS)3 3, RuH2(TPPTS)4 4, RuHI(TPPTS)3 5, RUCl2(CO)2(TPPTS)2 6 and [Ru(OAc)(CO)2(TPPTS)]2 7. Spectroscopic investigations have shown that in solution they have the same structures as their organosoluble analogues containing the ligand PPh3.

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页码：331 / 336

页数：6

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