STUDIES ON DIMETHYLHYDRAZONES OF HETEROARYL ALDEHYDES - THE REACTIVITY OF 2-FORMYLFURAN, 2-FORMYLTHIOPHENE AND 1-METHYL-2-FORMYLPYRROLE N,N-DIMETHYLHYDRAZONES WITH METHYL PROPIOLATE AND DIETHYL AZODICARBOXYLATE

被引：13

作者：

ABARCA, B

BALLESTEROS, R

GONZALEZ, E

SANCHO, P

SEPULVEDA, J

SORIANO, C

机构：

[1] Departamento de Química Orgánica, Facultad de Farmacia, Universidad de Valencia, 46010 Valencia

来源：

HETEROCYCLES | 1990年 / 31卷 / 10期

关键词：

D O I：

10.3987/COM-90-5477

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The title hydrazones react with methyl propiolate giving the new 2-heteroarylpyridines (4,5 and 6).The reaction with diethyl azodicarboxylate gives 1:1 Michael adducts except with formylthiophene hydrazone that gives the compound (14) a novel type of 1:1 adduct. © 1990.

引用

页码：1811 / 1817

页数：7

共 19 条

[1] CYCLOADDITION REACTIONS OF 3-VINYLTHIOPHEN [J].

ABARCA, B ;

BALLESTEROS, R ;

ENRIQUEZ, E ;

JONES, G .

TETRAHEDRON, 1987, 43 (01) :269-274

[2] CYCLOADDITION REACTIONS - A NEW TYPE OF CYCLOADDUCT FROM A SUBSTITUTED 2-VINYLTHIOPHEN AND DMAD [J].

ABARCA, B ;

BALLESTEROS, R ;

SORIANO, C .

TETRAHEDRON, 1987, 43 (05) :991-998

[3] CYCLO-ADDITION REACTIONS OF 2-VINYLTHIOPHEN [J].

ABARCA, B ;

BALLESTEROS, R ;

ENRIQUEZ, E ;

JONES, G .

TETRAHEDRON, 1985, 41 (12) :2435-2440

[4] SYNTHESIS OF NOR-ANATOXIN-A AND ANATOXIN-A [J].

CAMPBELL, HF ;

EDWARDS, OE ;

KOLT, R .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1977, 55 (08) :1372-1379

[5] REACTION OF 2-ARYLTROPANES WITH DIETHYL AZODICARBOXYLATE [J].

CLARKE, RL ;

GAMBINO, AJ ;

HECKELER, ML .

JOURNAL OF ORGANIC CHEMISTRY, 1978, 43 (24) :4589-4593

[6] On new compounds and fissions of azo-dicarbonic acid [J].

Diels, O ;

Paquin, M .

BERICHTE DER DEUTSCHEN CHEMISCHEN GESELLSCHAFT, 1913, 46 :2000-2013

[7] Information on azodicarbonic acid ester. [J].

Diels, O ;

Fritzsche, P .

BERICHTE DER DEUTSCHEN CHEMISCHEN GESELLSCHAFT, 1911, 44 :3018-3027

[8]

GONZALEZ ME, 1988, HETEROCYCLES, V27, P1227

[9]

HUISGEN H, 1954, LIEBIGS ANN CHEM, P590

[10] DIE ADDUKTE PRIMARER UND SEKUNDARER AMINE AN CARBONESTER DER ACETYLENREIHE UND IHRE KONFIGURATION [J].

HUISGEN, R ;

HERBIG, K ;

SIEGL, A ;

HUBER, H .

CHEMISCHE BERICHTE-RECUEIL, 1966, 99 (08) :2526-&

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