CORRELATION-EFFECTS IN THE VALENCE SHELLS OF ZNCL2 - A SYNCHROTRON-RADIATION PHOTOEMISSION-STUDY

被引：1

作者：

DESIMONE, M

ADAM, MY

STRANGES, S

CAULETTI, C

PIANCASTELLI, MN

机构：

[1] UNIV PARIS 11,LURE,F-91405 ORSAY,FRANCE

[2] UNIV ROMA TOR VERGATA,DIPARTIMENTO SCI & TECNOL CHIM,I-00173 ROME,ITALY

来源：

CHEMICAL PHYSICS | 1994年 / 187卷 / 1-2期

关键词：

D O I：

10.1016/0301-0104(94)00220-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The outer and inner valence shells of ZnCl2 are investigated by gas-phase synchrotron radiation photoemission. The branching ratios for the outer valence levels are reported in the photon energy region between 40 and 60 eV. The inner valence spectral features are observed for the first time. The most intense spectral structures of this region are assigned either to states with main character of Cl 3s or to Zn 3d satellites.

引用

收藏

页码：137 / 142

页数：6

相关论文

共 15 条

[1] SINGLE AND DOUBLE PHOTOIONISATION OF ATOMIC SILVER BETWEEN 43.5 AND 15.5 NM [J].

ADAM, MY ;

HELLNER, L ;

DUJARDIN, G ;

SVENSSON, A ;

MARTIN, P ;

FARNOUX, FC .

JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 1989, 22 (13) :2141-2150

[2] ELECTRONEGATIVITY VALUES FROM THERMOCHEMICAL DATA [J].

ALLRED, AL .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1961, 17 (3-4) :215-221

[3] HIGH-RESOLUTION HEI AND HEII PHOTOELECTRON-SPECTRA OF THE ZN 3D AND CD 4D ORBITALS IN THE ZINC AND CADMIUM DIHALIDES - LIGAND-FIELD SPLITTINGS AND INTENSITY VARIATIONS [J].

BANCROFT, GM ;

BRISTOW, DJ ;

TSE, JS .

CHEMICAL PHYSICS, 1983, 75 (02) :277-296

[4] PES OF HIGH-TEMPERATURE VAPORS .6. 304 A AND 584 A PES OF ZN, CD, AND HG HALIDES AND ELECTRONEGATIVITY SCALE [J].

BERKOWITZ, J .

JOURNAL OF CHEMICAL PHYSICS, 1974, 61 (01) :407-413

[5]

Boggess G. W., 1973, Journal of Electron Spectroscopy and Related Phenomena, V2, P467, DOI 10.1016/0368-2048(73)80061-1

[6] HIGH-RESOLUTION HEI AND HEII PHOTOELECTRON-SPECTRA OF THE ZINC AND CADMIUM DIHALIDE VALENCE BANDS [J].

BRISTOW, DJ ;

BANCROFT, GM ;

TSE, JS .

CHEMICAL PHYSICS, 1983, 75 (02) :263-275

[7] CORRELATION-EFFECTS IN THE IONIZATION OF MOLECULES - BREAKDOWN OF THE MOLECULAR-ORBITAL PICTURE [J].

CEDERBAUM, LS ;

DOMCKE, W ;

SCHIRMER, J ;

VONNIESSEN, W .

ADVANCES IN CHEMICAL PHYSICS, 1986, 65 :115-159

[8] PHOTOELECTRON SPECTRA OF ZINC AND CADMIUM HALIDES [J].

COCKSEY, BG ;

ELAND, JHD ;

DANBY, CJ .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS II, 1973, 69 (10) :1558-1561

[9] ORBITAL MOMENTUM DISTRIBUTIONS AND BINDING-ENERGIES FOR THE COMPLETE VALENCE SHELL OF MOLECULAR CHLORINE BY ELECTRON MOMENTUM SPECTROSCOPY [J].

FROST, L ;

GRISOGONO, AM ;

MCCARTHY, IE ;

WEIGOLD, E ;

BRION, CE ;

BAWAGAN, AO ;

MUKHERJEE, PK ;

VONNIESSEN, W ;

ROSI, M ;

SGAMELLOTTI, A .

CHEMICAL PHYSICS, 1987, 113 (01) :1-18

[10] MEASUREMENTS OF PARTIAL AND DIFFERENTIAL PHOTO-IONIZATION CROSS-SECTIONS OF HELIUM AND DIATOMIC-MOLECULES IN THE 15-100 EV RANGE BY ANGULAR ELECTRON-SPECTROSCOPY [J].

MORIN, P ;

ADAM, MY ;

NENNER, I ;

DELWICHE, J ;

HUBINFRANSKIN, MJ ;

LABLANQUIE, P .

NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH, 1983, 208 (1-3) :761-766