The complexes formed between a series of 19 different crown ethers and Fe(CO)(n)(+) ions are described. It is found that the energy released in the reactions increases with the crown ether ring size. The bicyclic-ring crown ethers can form sandwich type compounds with the reagent.
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Pohang Univ Sci & Technol POSTECH, Dept Chem, Pohang, South KoreaPohang Univ Sci & Technol POSTECH, Dept Chem, Pohang, South Korea
Noh, Dong Hun
Lee, Shin Jung C.
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Pohang Univ Sci & Technol POSTECH, Dept Chem, Pohang, South KoreaPohang Univ Sci & Technol POSTECH, Dept Chem, Pohang, South Korea
Lee, Shin Jung C.
Lee, Jong Wha
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Pohang Univ Sci & Technol POSTECH, Dept Chem, Pohang, South KoreaPohang Univ Sci & Technol POSTECH, Dept Chem, Pohang, South Korea
Lee, Jong Wha
Kim, Hugh I.
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Pohang Univ Sci & Technol POSTECH, Dept Chem, Pohang, South Korea
Pohang Univ Sci & Technol POSTECH, Div Adv Mat Sci, Pohang, South KoreaPohang Univ Sci & Technol POSTECH, Dept Chem, Pohang, South Korea