A NOVEL, SIMPLE AND CHEAP SOURCE OF ALKYL RADICALS FROM ALCOHOLS, USEFUL FOR HETEROAROMATIC SUBSTITUTION

被引：17

作者：

COPPA, F ^{[1
]}

FONTANA, F ^{[1
]}

LAZZARINI, E ^{[1
]}

MINISCI, F ^{[1
]}

PIANESE, G ^{[1
]}

ZHAO, LH ^{[1
]}

机构：

[1] POLITECN MILAN, DIPARTIMENTO CHIM, PIAZZA LEONARDO DA VINCI 32, I-20133 MILAN, ITALY

来源：

CHEMISTRY LETTERS | 1992年 / 07期

关键词：

D O I：

10.1246/cl.1992.1295

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Alkyl radicals were easily produced from secondary or tertiary alcohols in a cheap and simple way by silver-catalyzed decarboxylation of oxalic acid monoesters by S2O8=. They were utilized for the alkylation of heteroaromatic bases in a two-phase system, with high yields and selectivity.

引用

页码：1295 / 1298

页数：4

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