BASKET-SHAPED MOLECULAR CAVITY-CONTAINING DONOR CENTERS - SYNTHESIS, STRUCTURE, PROPERTIES

被引：13

作者：

BREITENBACH, J

RISSANEN, K

WOLF, UU

VOGTLE, F

机构：

[1] UNIV BONN,INST ORGAN CHEM & BIOCHEM,GERHARD DOMAGK STR 1,W-5300 BONN 1,GERMANY

[2] UNIV JYVASKYLA,DEPT CHEM,SF-40100 JYVASKYLA,FINLAND

[3] BAYER AG,W-4047 DORMAGEN,GERMANY

来源：

CHEMISCHE BERICHTE | 1991年 / 124卷 / 10期

关键词：

BASKET-SHAPED MOLECULES; PYRIDINE DERIVATIVES; MACROCYCLIC COMPOUNDS; HETEROCYCLIC COMPOUNDS; SUPRAMOLECULAR CHEMISTRY;

D O I：

10.1002/cber.19911241027

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The macrocyclic basket-shaped molecule 2, composed of three 4-donor-substituted pyridine units, is synthesized by cyclisation of the chloromethyl compound 7 with sulfonamide 8. The X-ray structure analysis of 2 gives an impression of the shape of the molecular basket. Furthermore it demonstrates that the toluenesulfonamide residues interlink, creating dimeric units of 2 in the crystal.

引用

页码：2323 / 2327

页数：5

共 16 条

[1] REACTION OF TOSYLAMIDE MONOSODIUM SALT WITH BIS(HALOMETHYL) COMPOUNDS - AN EASY ENTRY TO SYMMETRICAL N-TOSYL AZA MACROCYCLES [J].