TRYPTOPHAN ANION COMPLEXES OF BETA-CYCLODEXTRIN (CYCLOMALTAHEPTAOSE), AN AMINOPROPYLAMINO-BETA-CYCLODEXTRIN AND ITS ENANTIOSELECTIVE NICKEL(II) COMPLEX

被引：38

作者：

BROWN, SE ^{[1
]}

COATES, JH ^{[1
]}

EASTON, CJ ^{[1
]}

VANEYK, SJ ^{[1
]}

LINCOLN, SF ^{[1
]}

MAY, BL ^{[1
]}

STILE, MA ^{[1
]}

WHALLAND, CB ^{[1
]}

WILLIAMS, ML ^{[1
]}

机构：

[1] UNIV ADELAIDE, DEPT CHEM, ADELAIDE, SA 5005, AUSTRALIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 01期

关键词：

D O I：

10.1039/c39940000047

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

6'-(3-Aminopropylamino)-6'-deoxy-cyclomaltaheptaose (beta CDpn) exhibits enhanced complexation of tryptophan anion, by comparison with beta CD, while the nickel(II) complex of beta CDpn complexes tryptophan anion even more strongly and exhibits a tenfold enantioselectivity in favour of the (S)-tryptophan anion.

引用

页码：47 / 47

页数：1

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