GENERAL-APPROACH FOR THE SYNTHESIS OF POLYQUINENES VIA THE WEISS REACTION .12. THE CHUGAEV APPROACH TO ELLACENE (1,10-CYCLODODECANOTRIQUINANCENE)

被引：11

作者：

FU, XY ^{[1
]}

COOK, JM ^{[1
]}

机构：

[1] UNIV WISCONSIN,DEPT CHEM,MILWAUKEE,WI 53201

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 24期

关键词：

D O I：

10.1016/S0040-4039(00)97409-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of ellacene (1,10-cyclododecanotriquinancene) 2 has been achieved via the Weiss reaction. The regiospecific monoallylation of 6 to provide 7, and the pyrolysis of tris xanthate 11 in HMPA at 220°C to furnish 2 represent the key steps in the sequence. The HMPA-mediated dehydration of triol 10 to form the ethers 12 and 13 in preference to the desired 2 has also been observed. © 1990.

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页码：3409 / 3412

页数：4

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