CONTRIBUTION OF METAL-BONDED POLYCYCLIC AROMATIC-HYDROCARBONS TO THE INTERSTELLAR DEPLETION

被引:0
作者
KLOTZ, A
MARTY, P
BOISSEL, P
SERRA, G
CHAUDRET, B
DAUDEY, JP
机构
[1] UNIV TOULOUSE 3, CNRS, UPR 8241, CHIM COORDINAT LAB, F-31400 TOULOUSE, FRANCE
[2] INST NATL POLYTECH TOULOUSE, F-31400 TOULOUSE, FRANCE
[3] UNIV TOULOUSE 3, IRSAMC, PHYS QUANT LAB, CNRS, URA 505, F-31400 TOULOUSE, FRANCE
[4] UNIV PARIS 11, PHOTOPHYS MOLEC LAB, ORSAY, FRANCE
关键词
INTERSTELLAR MEDIUM; ABUNDANCES; (DEPLETION); MOLECULES (POLYCYCLIC AROMATIC HYDROCARBON); PHYSICAL DATA AND PROCESSES; MOLECULAR DATA (ORGANOMETALLIC BONDING ENERGIES);
D O I
暂无
中图分类号
P1 [天文学];
学科分类号
0704 ;
摘要
A satisfactory correlation is described between the bonding energy of a given metal coordinated to a PAH and its observed interstellar depletion. As a consequence, a modelling was elaborated based on the observed depletion of metals and on the theory of thermo-photo-dissociation of organometallic molecules. In this modelling, the abundance of organometallic species is calculated to explain about 5 to 10% of the depletion in the diffuse interstellar medium. Moreover, a constraint on the size distribution of PAHs is presented which is close to the standard distribution deduced by Desert et al. (1990) from a modelling of infrared radiations emitted by the interstellar matter.
引用
收藏
页码:520 / 530
页数:11
相关论文
共 53 条
[1]   ABUNDANCES OF THE ELEMENTS - METEORITIC AND SOLAR [J].
ANDERS, E ;
GREVESSE, N .
GEOCHIMICA ET COSMOCHIMICA ACTA, 1989, 53 (01) :197-214
[3]   MG+ -LIGAND BINDING-ENERGIES [J].
BAUSCHLICHER, CW ;
PARTRIDGE, H .
CHEMICAL PHYSICS LETTERS, 1991, 181 (2-3) :129-133
[4]   THEORETICAL-STUDY OF TRANSITION-METAL IONS BOUND TO BENZENE [J].
BAUSCHLICHER, CW ;
PARTRIDGE, H ;
LANGHOFF, SR .
JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (08) :3273-3278
[5]  
BIEMONT E, 1991, ASTRON ASTROPHYS, V249, P539
[6]   FORMATION OF ADDUCT IONS OF SI+(2P) WITH BENZENE AND NAPHTHALENE AND THEIR REACTIONS IN THE GAS-PHASE - GRAPHITIC SURFACE-CHEMISTRY IN THE GAS-PHASE [J].
BOHME, DK ;
WLODEK, S ;
WINCEL, H .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (17) :6396-6401
[7]  
BOISSEL P, 1994, ASTRON ASTROPHYS, V285, pL33
[8]   EXTENDED GAUSSIAN-TYPE VALENCE BASIS-SETS FOR CALCULATIONS INVOLVING NON-EMPIRICAL CORE PSEUDOPOTENTIALS [J].
BOUTEILLER, Y ;
MIJOULE, C ;
NIZAM, M ;
BARTHELAT, JC ;
DAUDEY, JP ;
PELISSIER, M ;
SILVI, B .
MOLECULAR PHYSICS, 1988, 65 (02) :295-312
[9]   THE ABUNDANCE OF HEAVY-ELEMENTS IN INTERSTELLAR GAS [J].
CARDELLI, JA .
SCIENCE, 1994, 265 (5169) :209-213
[10]  
CHAUDRET B, 1991, NEW J CHEM, V15, P791