CHIRAL DISCRIMINATION OF MONOSACCHARIDES THROUGH GEL FORMATION

被引：91

作者：

JAMES, TD ^{[1
]}

MURATA, K ^{[1
]}

HARADA, T ^{[1
]}

UEDA, K ^{[1
]}

SHINKAI, S ^{[1
]}

机构：

[1] RES DEV CORP JAPAN, ERATO, CHEMIRECOGNICS PROJECT, KURUME, FUKUOKA 830, JAPAN

来源：

CHEMISTRY LETTERS | 1994年 / 02期

关键词：

D O I：

10.1246/cl.1994.273

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The cholesteryl phenylboronic acid (1) and its complexes with mono saccharides (2:1; 1/monosaccharide) were prepared. Many of the isolated complexes form gels in a variety of solvents, some of which display D vs L chiral discrimination. This is the first example of chiral discrimination in a saccharide based gel system.

引用

页码：273 / 276

页数：4

共 15 条

[11] SOL-GEL PHASE-TRANSITION OF SWITCH-FUNCTIONALIZED CHOLESTEROLS AS DETECTED BY CIRCULAR-DICHROISM [J].

MURATA, K ;

AOKI, M ;

SHINKAI, S .

CHEMISTRY LETTERS, 1992, (05) :739-742

[12] ION PERMEATION THROUGH POLYMER-SUPPORTED STEROIDAL CROWN MEMBRANES [J].

SHINKAI, S ;

HE, GX ;

MATSUDA, T ;

SHIMAMOTO, K ;

NAKASHIMA, N ;

MANABE, O .

JOURNAL OF POLYMER SCIENCE PART C-POLYMER LETTERS, 1989, 27 (06) :209-213

[13] CROWN METAL INTERACTIONS IN CHOLESTERIC LIQUID-CRYSTALS [J].

SHINKAI, S ;

NISHI, T ;

IKEDA, A ;

MATSUDA, T ;

SHIMAMOTO, K ;

MANABE, O .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (04) :303-304

[14]

SHINKAI S, 1989, MAKROMOL CHEM-RAPID, V10, P361

[15] LIQUID-CRYSTALLINE SOLVENTS AS MECHANISTICS PROBES .30. THERMOTROPIC LIQUID-CRYSTALS AS REACTION MEDIA FOR MECHANISTIC INVESTIGATIONS [J].

WEISS, RG .

TETRAHEDRON, 1988, 44 (12) :3413-3475

← 1 2 →