ISOTOPE EFFECTS OF RUBIDIUM IN AMALGAM AQUEOUS-SOLUTION SYSTEMS

被引：9

作者：

CHANG, Z ^{[1
]}

HOSOE, M ^{[1
]}

NOMURA, M ^{[1
]}

FUJII, Y ^{[1
]}

机构：

[1] TOKYO INST TECHNOL,NUCL REACTOR RES LAB,MEGURO KU,TOKYO 152,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS | 1995年 / 91卷 / 15期

关键词：

D O I：

10.1039/ft9959102319

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The isotope separation factor, alpha, for rubidium isotopes in the rubidium amalgam/aqueous rubidium hydroxide system has been investigated as a function of temperature by both single-stage and multi-stage methods. At 293 K the single-stage separation factor for Rb-87-Rb-85 was found to be 1.000 70 +/- 0.000 06 by multi-stage experiments. The exothermic enthalpy of the isotope-exchange reaction was also estimated thermodynamically.

引用

页码：2319 / 2322

页数：4

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