REACTIONS OF MOLYBDENUM ARSENIC TETRAHEDRANES WITH FE2(CO)9 AND FE3(CO)12

被引：9

作者：

GORZELLIK, M ^{[1
]}

NUBER, B ^{[1
]}

ZIEGLER, ML ^{[1
]}

机构：

[1] UNIV HEIDELBERG,INST ANORGAN CHEM,W-6900 HEIDELBERG,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 436卷 / 02期

关键词：

D O I：

10.1016/0022-328X(92)85049-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

By co-photolysis of (mu3-As)(C5H4R)3Mo3(CO)6 (R = H (1a), R = Me (1b)) with Fe3(CO)12 (2) the clusters (mu4-As)(C5H4R)3Fe3Mo3(CO)17 (R = H) (3a), R = Me (3b)), (mu4-As)-(C5H4R)3FeMo3(CO)10 (R = H (4a), R = Me (4b)) and (mu4-As)(C5H4R)3Fe2Mo3(CO)12 (R = H (5a), R = Me (5b)) were synthesized. Thermal reaction of As2Cp2Mo2(CO)4 (6a) with Fe2(CO)9 (7) or Fe3(CO)12 (2) yields the complex (mu4-As)2Cp2Fe3Mo2(CO)15 (8) having the structure of a square pyramid. Co-photolysis of As2Cp'2Mo2(CO)4 (6b) (Cp' = C5H4Me) with Fe2(CO)9 (7) leads to the cluster As2Cp'2Mo2Fe4(CO)17 (9) with a mu5-As moiety. X-ray diffraction studies of 3a, 5b, 8 and 9 are described.

引用

页码：207 / 222

页数：16

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