DIRECT IR SPECTROSCOPIC STUDY OF THE CYCLOPENTADIENYL RADICAL

被引：15

作者：

KOROLEV, VA

NEFEDOV, OM

机构：

[1] N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, 117913

来源：

RUSSIAN CHEMICAL BULLETIN | 1993年 / 42卷 / 08期

关键词：

CYCLOPENTADIENYL RADICAL; MATRIX ISOLATION; INFRARED SPECTRUM;

D O I：

10.1007/BF00699952

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The products of vacuum pyrolysis of bis(cyclopentadienyl)nickel have been studied by matrix isolation infrared spetroscopy. Three IR bands at 3079, 1383 and 661 cm-1 corresponding to the cyclopentadienyl radical have been observed. A comparison of the IR spectrum of the radical .C5H5 with those of the ligand pi-C5H5 and free anion -C5H5 has been performed.

引用

页码：1436 / 1437

页数：2

共 6 条

[1]

ALEXANYAN VT, 1976, ITOGI NAUKI TEKHNIKI, V5

[2] FLASH VACUUM PYROLYSIS .4. ISOLATION AND REARRANGEMENT OF 9,10-DIHYDROFULVALENE [J].