TERT-BUTYLBENZAMIDATE DIRUTHENIUM(II, III) COMPOUNDS - CRYSTAL-STRUCTURE OF [RU-2(MU-HNOCC6H4-P-CME(3))(4)(OPPH(3))(2)]BF4

被引：11
作者：
BARRAL, MC
JIMENEZAPARICIO, R
PRIEGO, JL
ROYER, EC
URBANOS, FA
MONGE, A
RUIZVALERO, C
机构：
[1] UNIV COMPLUTENSE,FAC CIENCIAS QUIM,DEPT QUIM INORGAN,E-28040 MADRID,SPAIN
[2] CSIC,INST CIENCIA MAT,E-28006 MADRID,SPAIN
[3] UNIV COMPLUTENSE,FAC CIENCIAS QUIM,RAYOS X LAB,E-28040 MADRID,SPAIN
来源：
POLYHEDRON | 1993年 / 12卷 / 24期
关键词：
D O I：
10.1016/S0277-5387(00)80044-3
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction between RU(2)Cl(mu-O2CCH3)(4) and molten p-tert-butylbenzamide led to the formation of Ru2Cl(mu-HNOCC6H4-p-CMe(3))(4). The polymeric structure of this insoluble compound was broken with AgBF4, in anhydrous thf, giving [Ru-2(mu-HNOCC6H4-p-CMe(3))(4)(thf)(2)]BF4. The reaction of this cationic complex with OPPh(3) gave [Ru-2(mu-HNOCC6H4-p-CMe(3))(4)(OPPH3)(2)]BF4. The compounds have been characterized by elemental analysis, spectroscopic data and magnetic measurements and the crystal structure of [Ru-2(mu 1-HNOCC6H4-p-CMe(3))(4)(OPPh(3))(2)]BF4 was determined by X-ray crystallography. The asymmetric unit is composed of halves of two different crystallographically independent centrosymmetric cations. Each ruthenium(II,III) dimer is bonded to four bridging p-tert-butylbenzamidate ligands and to two axial triphenylphosphine oxide molecules. The Ru-Ru distances in the two dimeric cations of the unit cell are 2.281(2) and 2.280(2) Angstrom. The compound has a non-polar 2:2 arrangement of the tert-butylbenzamidate ligands.
引用
收藏
页码：2947 / 2953
页数：7
相关论文
共 28 条
[1]   SYNTHESIS AND STRUCTURE OF A NEW COMPLEX OF RUTHENIUM CONTAINING THE TETRA(MU-TERTBUTYLBENZOATE)DIRUTHENIUM(II,III) UNIT [J].
BARRAL, MC ;
JIMENEZAPARICIO, R ;
PRIEGO, JL ;
ROYER, EC ;
GUTIERREZPUEBLA, E ;
VALERO, CR .
POLYHEDRON, 1992, 11 (17) :2209-2215
[2]   SYNTHESIS AND CHARACTERIZATION OF NEW CARBOXYLATE DIMERS OF RUTHENIUM [J].
BARRAL, MC ;
JIMENEZAPARICIO, R ;
RIAL, C ;
ROYER, E ;
SAUCEDO, MJ ;
URBANOS, FA .
POLYHEDRON, 1990, 9 (14) :1723-1728
[3]   ELECTROCHEMICAL STUDIES ON 3 POLAR DIRUTHENIUM(II,III) COMPLEXES [J].
CHAKRAVARTY, AR ;
COTTON, FA ;
TOCHER, DA ;
TOCHER, JH .
POLYHEDRON, 1985, 4 (08) :1475-1478
[4]   A NEW MIXED-LIGAND DIRUTHENIUM(II) COMPOUND - SYNTHESIS AND CHARACTERIZATION OF "[RU2CL(ME2PCH2PME2)2(PHNPY)2][BPH4] [J].
CHAKRAVARTY, AR ;
COTTON, FA ;
FALVELLO, LR .
INORGANIC CHEMISTRY, 1986, 25 (02) :214-219
[5]   SYNTHESIS AND MOLECULAR-STRUCTURE OF RU2(C5NH4NH)6(PME2PH)2, A RU RU-BONDED MOLECULE WITH 2-PYRIDINYLAMIDE LIGANDS IN 3 COORDINATION MODES AND OTHER NOVEL FEATURES [J].
CHAKRAVARTY, AR ;
COTTON, FA ;
TOCHER, DA .
INORGANIC CHEMISTRY, 1984, 23 (24) :4030-4033
[6]   DISPLACIVE TRANSFER OF A PHENYL GROUP FROM TRIPHENYLPHOSPHINE TO A METAL ATOM - SYNTHESIS AND MOLECULAR-STRUCTURE OF RU2PH2(PHCONH)2[PH2POC(PH)N]2 [J].
CHAKRAVARTY, AR ;
COTTON, FA ;
TOCHER, DA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (21) :6409-6413
[7]   SYNTHESIS AND STRUCTURE OF A BINUCLEAR RUTHENIUM 4-CHLOROBENZAMIDATO COMPLEX [J].
CHAKRAVARTY, AR ;
COTTON, FA ;
TOCHER, DA .
POLYHEDRON, 1985, 4 (06) :1097-1102
[8]   MIXED-LIGAND COMPLEXES OF DIRUTHENIUM(II, III) - SYNTHESES AND MOLECULAR-STRUCTURES OF CHLORO-BIS-(ACETATO)-BIS-(2-ANILINOPYRIDINATO)(2-ANILINOPYRIDINE)-DIRUTHENIUM.METHYLENE CHLORIDE AND CHLORO-(ACETATO)-TRIS(6-CHLORO-2-OXYPYRIDINATO)DIRUTHENIUM.METHYLENE CHLORIDE [J].
CHAKRAVARTY, AR ;
COTTON, FA .
INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS, 1985, 105 (01) :19-29
[9]   A NEW DIRUTHENIUM(II,III) COMPOUND, RU2(C=CPH)(PHNPY)4.2CH2CL2, WITH AN AXIAL ETA-1-ACETYLIDE LIGAND [J].
CHAKRAVARTY, AR ;
COTTON, FA .
INORGANICA CHIMICA ACTA, 1986, 113 (01) :19-26
[10]   SYNTHESES, MOLECULAR-STRUCTURES, AND PROPERTIES OF 2 POLAR DIRUTHENIUM(II,III) COMPLEXES OF 2-HYDROXYPYRIDINE AND 2-ANILINOPYRIDINE [J].
CHAKRAVARTY, AR ;
COTTON, FA ;
TOCHER, DA .
INORGANIC CHEMISTRY, 1985, 24 (02) :172-177
123