THE EFFECT OF TENSIOACTIVE AGENTS ON THE KINETICS OF HYDROGEN EVOLUTION AT A NICKEL ELECTRODE

被引：1
|
作者：
MENINI, R
WRONA, PK
MENARD, H
VITTORI, O
机构：
来源：
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE | 1992年 / 70卷 / 12期
关键词：
D O I：
10.1139/v92-376
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The effect of tensioactive agents (TSA = SDS, BRIJ35, BRIJ78, BRIJ99, and CTAB) on the kinetics of hydrogen evolution at a rotating nickel electrode in 0.2 M solutions of Na2SO4 was investigated. It was found that at higher concentrations of TSA, their presence inhibited the reaction although their adsorption behaviour at the nickel electrode is different. We concluded that BRIJ35 and CTAB should show better performance in the hydrogenation of organic compounds than SDS.
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页码：2948 / 2953
页数：6
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