HYDROFORMYLATION OF CHIRAL TERPENES WITH PTCL(SNCL3)-(BIS-PHOSPHINE) AS CATALYST

被引：43
作者：
KOLLAR, L
BAKOS, J
HEIL, B
SANDOR, P
SZALONTAI, G
机构：
[1] HUNGARIAN ACAD SCI,CENT RES INST CHEM,H-1025 BUDAPEST,HUNGARY
[2] RES INST HEAVY CHEM IND,H-8201 VESZPREM,HUNGARY
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 385卷 / 01期
关键词：
D O I：
10.1016/0022-328X(90)87153-5
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
(+)-R-Limonene and (-)-R-carvone undergo hydroformylation in the presence of catalytic Pt-bisphosphine-SnCl2 systems to yield exclusively the linear products. The internal double bond and the carbonyl group remain intact in both substrates during the reaction. The variation of the diastereomeric composition of the aldehydes upon variation of the chelating phosphine in the catalyst has been investigated. © 1990.
引用
收藏
页码：147 / 152
页数：6
相关论文
共 9 条
[1]   A FACILE METHOD FOR THE PREPARATION OF 2,4-BIS(DIPHENYLPHOSPHINO)PENTANE (BDPP) ENANTIOMERS AND THEIR APPLICATION IN ASYMMETRIC HYDROGENATION [J].
BAKOS, J ;
TOTH, I ;
HEIL, B ;
MARKO, L .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 279 (1-2) :23-29
[2]  
BORDENCA C, 1952, Patent No. 2584539
[3]   ADVANCES IN THE HYDROFORMYLATION OF OLEFINS CONTAINING FUNCTIONAL-GROUPS [J].
BOTTEGHI, C ;
GANZERLA, R ;
LENARDA, M ;
MORETTI, G .
JOURNAL OF MOLECULAR CATALYSIS, 1987, 40 (02) :129-182
[4]  
CONSIGLIO G, 1982, TOP CURR CHEM, V77
[5]  
HIMMELE W, 1976, TETRAHEDRON LETT, V12, P907
[6]   ASYMMETRIC HYDROFORMYLATION OF UNSATURATED ESTERS WITH PTCL(SNCL3)[(R,R)-DIOP] CATALYST [J].
KOLLAR, L ;
CONSIGLIO, G ;
PINO, P .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 330 (1-2) :305-314
[7]   TEMPERATURE-DEPENDENCE OF THE ASYMMETRIC INDUCTION IN THE PTCL(SNCL3)[(-)-(2S,4S)-2,4-BIS(DIPHENYLPHOSPHINO)PENTANE]-CATALYZED ENANTIOSELECTIVE HYDROFORMYLATION REACTION [J].
KOLLAR, L ;
BAKOS, J ;
TOTH, I ;
HEIL, B .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 350 (02) :277-284
[8]   ASYMMETRIC HYDROFORMYLATION CATALYZED BY HOMOGENEOUS AND POLYMER-SUPPORTED PLATINUM COMPLEXES CONTAINING CHIRAL PHOSPHINE-LIGANDS [J].
PARRINELLO, G ;
STILLE, JK .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (23) :7122-7127
[9]  
Siegel H., 1980, ANGEW CHEM, V92, P182
1