CARBONYLATION OF THE TRIPLY BONDED DIRHENIUM(II) COMPLEXES RE2X4(DPPM)2(X=CL,BR - DPPM=PH2PCH2PPH2 TO GIVE [RE2X3(DPPM)2(CO)2]PF6 - STRUCTURAL CHARACTERIZATION OF [(CO)CIRE(MU-CL)(MU-CO)(MU-DPPM)2RECL(CO)]PF6

被引：26

作者：

FANWICK, PE ^{[1
]}

PRICE, AC ^{[1
]}

WALTON, RA ^{[1
]}

机构：

[1] PURDUE UNIV,DEPT CHEM,W LAFAYETTE,IN 47907

来源：

INORGANIC CHEMISTRY | 1987年 / 26卷 / 23期

关键词：

D O I：

10.1021/ic00270a020

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

引用

页码：3920 / 3926

页数：7

共 50 条

[21] Reactions of the dirhenium(II) complexes Re2X4(dppm)2 (X=Cl, Br, dppm=Ph2PCH2PPh2) with isocyanides VI. Further studies on isomers of the edge-sharing bioctahedral species [Re2Cl3(ae-dppm)2(CO)(CNxyl)2]+$ /
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[22] REACTIONS OF THE ELECTRON-RICH TRIPLY BONDED DIRHENIUM(II) COMPLEXES RE2X4(MU-DPPM)2 (X = CL, BR) WITH DIOXYGEN .2. THE SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE COMPLEXES REOCL3(DPPMO) (DPPMO = PH2PCH2P(O)PH2) AND RE2(MU-O)CL6(MU-DPPM)2
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[23] REACTIONS OF THE DICARBONYL COMPLEXES RE2X4(DPPM)2(CO)2 (X = CL, BR) AND THE MIXED CARBONYL ISOCYANIDE COMPLEXES RE2CL4(DPPM)2(CO)(CNR) (R = T-BU, XYLYL) WITH TRIMETHYLPHOSPHINE AND TRIALKYL PHOSPHITE LIGANDS - STRUCTURAL CHARACTERIZATION OF THE COMPLEXES [RE2CL3(MU-DPPM)2(CO)2L]PF6 (L = PME3, P(OET)3) THAT CONTAIN AN UNSYMMETRICAL CARBONYL BRIDGE
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[24] Reactions of the dirhenium(II) complexes Re2X4(μ-dppm)2 (X = Cl, Br; dppm = Ph2PCH2PPh2) with isocyanides.: 18.: The isolation and characterization of isomers of the [Re2Cl2(μ-dppm)2(CO)(CNXyl)3]2+ cation and its monocationic and neutral congeners
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[25] Reactions of the dirhenium(II) complexes Re2X4(μ-dppm)2 (X = Cl, Br; dppm = Ph2PCH2PPh2) with isocyanides.: 19.: Studies of the reactions of five structural isomers of Re2Cl2(μ-dppm)2(CO)(CNXyl)3 that lead to the dirhenium(I) complexes [Re2(μ-Cl)(μ-CO)(μ-dppm)2(CNXyl)4]O3SCF3 and [Re2Cl(μ-dppm)2(CO)(CNXyl)3(NCCH3)]O3SCF3
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[26] REACTIONS OF [PD2(MU-DPPM)2CL2] WITH ELECTROPHILIC COMPLEXES OF COPPER AND GOLD - SYNTHESIS OF THE PD4 CLUSTER [PD4(MU-CL)2(MU-DPPM)4](PF6)2.2(CH3)2CO
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[27] FURTHER-STUDIES ON THE REACTIVITY OF COMPLEXES OF THE TYPE CIS-RE2(MU-O2CR)2X2(MU-DPPM)2 - THE STRUCTURAL CHARACTERIZATION OF CIS-RE2(MU-O2CCH3)2(NCBH3)2(MU-DPPM)2 AND [RE2CL3(MU-DPPM)2(1,2-C6H4(CN)2)2]PF6
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[29] ELECTRON-DONOR ABILITY OF THE UNSATURATED DIMANGANESE HYDRIDES [MN2(MU-X)(MU-H)(CO)6(MU-DPPM)] (X = H, AUPPH3 DPPM = PH2PCH2PPH2) - X-RAY CRYSTAL-STRUCTURES OF [MN2(MU-AG(CLO4)PPH3)(MU-H)2(CO)6(MU-DPPM)] AND [MN2(MU-AUPPH3)2(MU-H)(CO)6(MU-DPPM)][PF6].C7H8
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[30] REACTIONS OF THE DIRHENIUM(II) COMPLEXES [RE2X4(DPPM)2] (X = CL OR BR, DPPM = PH2PCH2PPH2) WITH ISOCYANIDES .2. THE A-FRAME-LIKE MONOISOCYANIDE SPECIES [RE2(MU-X)(MU-DPPM)2X3(CNR)]N+ (R = ME, BUT, OR C6H3ME2-2,6,N = 0 OR 1)
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