UNUSUAL TRANSFORMATIONS OF ETHYL-2-CYANOACRYLATE IN REACTIONS WITH TRIVALENT PHOSPHORUS-COMPOUNDS

被引：16

作者：

GOLOLOBOV, YG

KOLOMNIKOVA, GD

KRYLOVA, TO

机构：

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 11期

关键词：

D O I：

10.1016/0040-4039(94)88337-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Interaction of ethyl-2-cyanoacrylate 1 with trivalent phosphorus compounds can cause not only polymerization of 1, but under established conditions it affords, depending on the structure of the latter, betaines 3, spirophosphoranes 5, i.e. phosphorylated at the carbonyl oxygen esters of 2-cyanopropionic acid or 2-cyano-3-phosphoranylpropionates 9.

引用

页码：1751 / 1754

页数：4