NEW PENTANUCLEAR CARBONYL RUTHENIUM CLUSTERS CONTAINING A SULFIDO LIGAND - SYNTHESIS AND STRUCTURE OF [N(PPH3)2]2[RU5(CO)14S]

被引：21

作者：

BODENSIECK, U ^{[1
]}

MEISTER, G ^{[1
]}

STOECKLIEVANS, H ^{[1
]}

SUSSFINK, G ^{[1
]}

机构：

[1] UNIV NEUCHATEL,INST CHIM,AVE BELLEVAUX 51,CH-2000 NEUCHATEL,SWITZERLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1992年 / 13期

关键词：

D O I：

10.1039/dt9920002131

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new series of pentanuclear sulfido clusters [Ru5(CO)14S]2- 1, [Ru5H(CO)14S]- 2 and [Ru5H2(CO)14S] 3 have been prepared; the monoanion 2, accessible from [Ru3(CO)12] and SC(NMe2)2, gives 1 upon deprotonation and 3 upon protonation.

引用

页码：2131 / 2132

页数：2

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[1] New class of ruthenium sulfide clusters:: Ru4S6(PPh3)4, Ru5S6(PPh3)5, and Ru6S8(PPh3)6 [J].

Eckermann, AL ;

Wunder, M ;

Fenske, D ;

Rauchfuss, TB ;

Wilson, SR .

INORGANIC CHEMISTRY, 2002, 41 (08) :2004-2006

[2] Synthesis and structure of Ru5(μ5-C2PPh2)(μ-dppm)(μ-PPh2)(CO)11•thf [J].

Adams, CJ ;

Bruce, MI ;

Skelton, BW ;

White, AH .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1999, 52 (05) :409-411

[3] REACTIVITY OF RH4(CO)12 WITH HALIDES OR PSEUDOHALIDES - SYNTHESIS OF THE PENTANUCLEAR CARBONYL CLUSTERS [RH5(CO)14X]N- (X = CL, BR, I, SCN, N = 2, X = PPH3, N = 1) - CRYSTAL-STRUCTURES OF [N(PPH3)2][RH5(MU-CO)6(CO)8(PPH3)] AND [N(PPH3)2]2[RH5(MU-CO)6(CO)8(SCN)] [J].

FUMAGALLI, A ;

MARTINENGO, S ;

GALLI, D ;

ALLEVI, C ;

CIANI, G ;

SIRONI, A .

INORGANIC CHEMISTRY, 1990, 29 (07) :1408-1413

[4] SYNTHESIS AND CHARACTERIZATION OF PENTANUCLEAR FE-IR CARBONYL CLUSTERS - SOLID-STATE STRUCTURES OF [N(PPH3)2]2[FELR4(CO)15] AND [PPH4][FE2LR3(CO)14] [J].

DELLAPERGOLA, R ;

GARLASCHELLI, L ;

DEMARTIN, F ;

MANASSERO, M ;

MASCIOCCHI, N ;

SANSONI, M ;

FUMAGALLI, A .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1989, (06) :1109-1116

[5] SYNTHESIS OF PENTANUCLEAR CLUSTERS DERIVED FROM [RU3RHH2(CO)10(PPH3)(MU-COME)] - CRYSTAL-STRUCTURES OF [RU3RH2H2(CO)12(PPH3)2] AND [RU3RHAUH(CO)10(PPH3)2-(MU-3-COME)] [J].

EVANS, J ;

STROUD, PM ;

WEBSTER, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (04) :1017-1023

[6] The ruthenium pyrazolonate complex Ru(PMIP)2(PPh3)2: Synthesis, structure, and some properties [J].

Platonova, E. O. ;

Baranov, E. V. ;

Bochkarev, L. N. ;

Kurskii, Yu A. .

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2012, 38 (11) :696-702

[7] Stabilisation of alkynyl dithiocarboxylates at a ruthenium centre:: X-ray crystal structures of [Ru(H)(CO)(S2CCCPh)(PPh3)2], [Ru(CO)(CPhCHPh)(S2CCCPh)(PPh3)2] and [Ru(CO)(CCMes)(S2CCCPh)(PPh3)2] [J].

Adams, H ;

McHugh, PE ;

Morris, MJ ;

Spey, SE ;

Wright, PJ .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 619 (1-2) :209-217

[8] The ruthenium pyrazolonate complex Ru(PMIP)2(PPh3)2: Synthesis, structure, and some properties [J].

E. O. Platonova ;

E. V. Baranov ;

L. N. Bochkarev ;

Yu. A. Kurskii .

Russian Journal of Coordination Chemistry, 2012, 38 :696-702

[9] FACILE RU-RU BOND-CLEAVAGE AND REFORMATION IN A PENTANUCLEAR CARBONYL CLUSTER - SYNTHESIS AND X-RAY STRUCTURAL STUDIES OF RU5(CO)13(MU-4-ETA-2-C=CPH) (MU-PPH2) AND ITS CO ADDUCT RU5(CO)14(MU-5-ETA-2-C=CPH) (MU-PPH2) [J].

MACLAUGHLIN, SA ;

TAYLOR, NJ ;

CARTY, AJ .

ORGANOMETALLICS, 1983, 2 (09) :1194-1202

[10] Synthesis and reactivity of Ru(PPh3)3(CO)HF and the N-heterocyclic carbene derivatives Ru(NHC)(PPh3)2(CO)HF [J].

Reade, Steven P. ;

Nama, Devendrababu ;

Mahon, Mary F. ;

Pregosin, Paul S. ;

Whittlesey, Michael K. .

ORGANOMETALLICS, 2007, 26 (14) :3484-3491

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