POLYMERIZATION OF OLEFINS THROUGH HETEROGENEOUS CATALYSIS .2. KINETICS OF GAS-PHASE PROPYLENE POLYMERIZATION WITH ZIEGLER-NATTA CATALYSTS

被引：42

作者：

CHOI, KY

RAY, WH

机构：

[1] Univ of Wisconsin-Madison, Dep of, Chemical Engineering, Madison, WI,, USA, Univ of Wisconsin-Madison, Dep of Chemical Engineering, Madison, WI, USA

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 1985年 / 30卷 / 03期

关键词：

CATALYSTS - CHEMICAL REACTIONS - Reaction Kinetics - GASES - HYDROGEN - MATHEMATICAL TECHNIQUES;

D O I：

10.1002/app.1985.070300315

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Propylene was polymerized in gas phase over a TiCl//3 multiplied by (times) 1/3 AlCl//3 (Stauffer Type AA) Catalyst with AlEt//2Cl cocatalyst both with and without H//2 present. The effects of polymerization temperature, monomer concentration, catalyst composition, and hydrogen were investigated. The experiments were carried out at operating conditions approaching industrial practice.

引用

页码：1065 / 1081

页数：17

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