ASYMMETRIC-SYNTHESIS BY ENZYMATIC-HYDROLYSIS OF PROCHIRAL DIENOL DIACETATE

被引：8
|
作者：
DUHAMEL, P [1 ]
RENOUF, P [1 ]
CAHARD, D [1 ]
YEBGA, A [1 ]
POIRIER, JM [1 ]
机构：
[1] INST RECH CHIM ORGAN FINE,F-76821 MONT ST AIGNAN,FRANCE
来源：
TETRAHEDRON-ASYMMETRY | 1993年 / 4卷 / 12期
关键词：
D O I：
10.1016/S0957-4166(00)82222-3
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Enzymatic hydrolysis of prochiral dienol diacetate 1 by Candida cylindracea lipase (C C L) leads to the keto enol acetate 2 in high yield with an enantiomeric excess > 98 %. The S configuration of the asymmetric center was assigned.
引用
收藏
页码：2447 / 2450
页数：4
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